Catalyst nucleation and carbon nanotube growth from flame-synthesized Co-Al-O nanopowders at ten-second time scale

Hiroyuki Shirae, Kei Hasegawa, Hisashi Sugime, Eongyu Yi, Richard M. Laine, Suguru Noda

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Flame-synthesized (CoO)x(Al2O3)1-x spinel nanopowders with primary particles of ∼20 nm were used to grow small diameter carbon nanotubes (CNTs). The nanopowders with x ≤ 0.35 grew few CNTs whereas that with x = 0.65 grew CNTs efficiently. Low crystalline and large-diameter multi-wall CNTs grew by annealing and chemical vapor deposition (CVD) at 800 °C for ∼10 min, whereas single-wall CNTs with high crystallinity (G-band to D-band intensity ratio of 20–100 by Raman spectroscopy) grew by annealing and CVD at ≥1000 °C for ∼10 s. The excess Co in the spinel reduced and segregated to form multiple Co nanoparticles on the surface of the single primary alumina nanoparticles in ∼10 s, yielding SWCNTs in ∼10 s. Such flame synthesized nanopowders, reduced and activated by H2, provide CNTs from C2H2, all in ten-second time scale, and as such are promising for practical, high-through-put production of small-diameter CNTs.

Original languageEnglish
Pages (from-to)31-38
Number of pages8
JournalCarbon
Volume114
DOIs
Publication statusPublished - 2017 Apr 1

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Carbon Nanotubes
Carbon nanotubes
Nucleation
Catalysts
Chemical vapor deposition
Annealing
Nanoparticles
Aluminum Oxide
Raman spectroscopy
Alumina
Crystalline materials

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Catalyst nucleation and carbon nanotube growth from flame-synthesized Co-Al-O nanopowders at ten-second time scale. / Shirae, Hiroyuki; Hasegawa, Kei; Sugime, Hisashi; Yi, Eongyu; Laine, Richard M.; Noda, Suguru.

In: Carbon, Vol. 114, 01.04.2017, p. 31-38.

Research output: Contribution to journalArticle

Shirae, Hiroyuki ; Hasegawa, Kei ; Sugime, Hisashi ; Yi, Eongyu ; Laine, Richard M. ; Noda, Suguru. / Catalyst nucleation and carbon nanotube growth from flame-synthesized Co-Al-O nanopowders at ten-second time scale. In: Carbon. 2017 ; Vol. 114. pp. 31-38.
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