Abstract
We examined oxidative coupling of methane (OCM) and oxidative dehydrogenation of ethane (ODE) over various polyoxometalate supported CeO2 catalysts at 423K in an electric field. Tetrabutylammonium (TBA) salt of Keggin-type phosphotungstate (PW12O40) supported CeO2 catalysts ((TBA)3PW12O40/CeO2) showed high activities for OCM and ODE in the electric field (3mA) at 423K, although the catalyst without the electric field showed extremely low activities at such low temperature. FT-IR spectra and XRD patterns confirmed that the structure of (TBA)3PW12O40/CeO2 was changed to Ce2(WO4)3/CeO2 after reactions with the electric field, and it acted as an active site structure for OCM and ODE with the electric field. Results of activity tests revealed that the C2H6 production was a main reaction in OCM with the electric field, and C2H4 was formed through a successive oxidative dehydrogenation of the formed C2H6. Periodic operation tests demonstrated that reactive oxygen species suitable for ODE were formed on the catalyst surface of Ce2(WO4)3 in the electric field.
| Original language | English |
|---|---|
| Journal | Catalysis Today |
| DOIs | |
| Publication status | Accepted/In press - 2016 Oct 31 |
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Keywords
- C-H bond dissociation
- Cerium tungstate
- Electric field
- Ethane oxidative dehydrogenation
- Methane oxidative coupling
- Polyoxometalate
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
Cite this
Catalytic oxidative conversion of methane and ethane over polyoxometalate-derived catalysts in electric field at low temperature. / Ogo, Shuhei; Iwasaki, Kousei; Sugiura, Kei; Sato, Ayaka; Yabe, Tomohiro; Sekine, Yasushi.
In: Catalysis Today, 31.10.2016.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Catalytic oxidative conversion of methane and ethane over polyoxometalate-derived catalysts in electric field at low temperature
AU - Ogo, Shuhei
AU - Iwasaki, Kousei
AU - Sugiura, Kei
AU - Sato, Ayaka
AU - Yabe, Tomohiro
AU - Sekine, Yasushi
PY - 2016/10/31
Y1 - 2016/10/31
N2 - We examined oxidative coupling of methane (OCM) and oxidative dehydrogenation of ethane (ODE) over various polyoxometalate supported CeO2 catalysts at 423K in an electric field. Tetrabutylammonium (TBA) salt of Keggin-type phosphotungstate (PW12O40) supported CeO2 catalysts ((TBA)3PW12O40/CeO2) showed high activities for OCM and ODE in the electric field (3mA) at 423K, although the catalyst without the electric field showed extremely low activities at such low temperature. FT-IR spectra and XRD patterns confirmed that the structure of (TBA)3PW12O40/CeO2 was changed to Ce2(WO4)3/CeO2 after reactions with the electric field, and it acted as an active site structure for OCM and ODE with the electric field. Results of activity tests revealed that the C2H6 production was a main reaction in OCM with the electric field, and C2H4 was formed through a successive oxidative dehydrogenation of the formed C2H6. Periodic operation tests demonstrated that reactive oxygen species suitable for ODE were formed on the catalyst surface of Ce2(WO4)3 in the electric field.
AB - We examined oxidative coupling of methane (OCM) and oxidative dehydrogenation of ethane (ODE) over various polyoxometalate supported CeO2 catalysts at 423K in an electric field. Tetrabutylammonium (TBA) salt of Keggin-type phosphotungstate (PW12O40) supported CeO2 catalysts ((TBA)3PW12O40/CeO2) showed high activities for OCM and ODE in the electric field (3mA) at 423K, although the catalyst without the electric field showed extremely low activities at such low temperature. FT-IR spectra and XRD patterns confirmed that the structure of (TBA)3PW12O40/CeO2 was changed to Ce2(WO4)3/CeO2 after reactions with the electric field, and it acted as an active site structure for OCM and ODE with the electric field. Results of activity tests revealed that the C2H6 production was a main reaction in OCM with the electric field, and C2H4 was formed through a successive oxidative dehydrogenation of the formed C2H6. Periodic operation tests demonstrated that reactive oxygen species suitable for ODE were formed on the catalyst surface of Ce2(WO4)3 in the electric field.
KW - C-H bond dissociation
KW - Cerium tungstate
KW - Electric field
KW - Ethane oxidative dehydrogenation
KW - Methane oxidative coupling
KW - Polyoxometalate
UR - http://www.scopus.com/inward/record.url?scp=85018927634&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85018927634&partnerID=8YFLogxK
U2 - 10.1016/j.cattod.2017.05.013
DO - 10.1016/j.cattod.2017.05.013
M3 - Article
AN - SCOPUS:85018927634
JO - Catalysis Today
JF - Catalysis Today
SN - 0920-5861
ER -