Catechol End-Capped Poly(arylene sulfide) as a High-Refractive-Index "tiO2/ZrO2-Nanodispersible" Polymer

Seigo Watanabe, Kenichi Oyaizu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Poly(arylene sulfide)s (PASs) with a functional group at one terminus were successfully prepared by end functionalization of a disulfide end in a precursor PAS obtained via oxidative polymerization. End functionalization of methoxy-substituted PAS (OMePPS) with a carboxylic acid or catechol unit afforded not only high refractive indices up to 1.7 but also a high dispersivity of TiO2/ZrO2 nanoparticles with a size of a few 30 nm, owing to the high affinity of the end group for inorganic oxide nanoparticles. In particular, the catechol-functionalized OMePPS showed remarkably high dispersivity of inorganic nanoparticles, and the hybrid film of this polymer with 30 wt % of ZrO2 nanoparticles exhibited a higher refractive index of 1.82 at the D line (589.3 nm).

Original languageEnglish
Pages (from-to)4495-4503
Number of pages9
JournalACS Applied Polymer Materials
Volume3
Issue number9
DOIs
Publication statusPublished - 2021 Sep 10

Keywords

  • composites
  • end functionalization
  • high refractive index
  • poly(phenylene sulfide)
  • polymer-inorganic nanohybrid materials
  • polymers

ASJC Scopus subject areas

  • Polymers and Plastics
  • Process Chemistry and Technology
  • Organic Chemistry

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