Cationic platinum-catalyzed etherification by intra- and intermolecular dehydration of alcohols

Takanori Shibata; Ryo Fujiwara; Yasunori Ueno

doi:10.1055/s-2004-835664

Cationic platinum-catalyzed etherification by intra- and intermolecular dehydration of alcohols

Takanori Shibata^*, Ryo Fujiwara, Yasunori Ueno

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

Catalytic etherification of diols proceeds to give various cyclic ethers by use of cationic platinum salt, which is in situ prepared from PtCl₂ and AgSbF₆. Etherification of benzylic alcohols is also possible by intermolecular dehydration. Both of intra- and intermolecular etherifications smoothly proceed even under an atmosphere of air.

Original language	English
Article number	U26004ST
Pages (from-to)	152-154
Number of pages	3
Journal	Synlett
Issue number	1
DOIs	https://doi.org/10.1055/s-2004-835664
Publication status	Published - 2005 Jan 5

Keywords

Alcohols
Dehydration
Diols
Ethers
Platinum

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-2004-835664

Cite this

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abstract = "Catalytic etherification of diols proceeds to give various cyclic ethers by use of cationic platinum salt, which is in situ prepared from PtCl2 and AgSbF6. Etherification of benzylic alcohols is also possible by intermolecular dehydration. Both of intra- and intermolecular etherifications smoothly proceed even under an atmosphere of air.",

keywords = "Alcohols, Dehydration, Diols, Ethers, Platinum",

author = "Takanori Shibata and Ryo Fujiwara and Yasunori Ueno",

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AU - Shibata, Takanori

AU - Fujiwara, Ryo

AU - Ueno, Yasunori

PY - 2005/1/5

Y1 - 2005/1/5

N2 - Catalytic etherification of diols proceeds to give various cyclic ethers by use of cationic platinum salt, which is in situ prepared from PtCl2 and AgSbF6. Etherification of benzylic alcohols is also possible by intermolecular dehydration. Both of intra- and intermolecular etherifications smoothly proceed even under an atmosphere of air.

AB - Catalytic etherification of diols proceeds to give various cyclic ethers by use of cationic platinum salt, which is in situ prepared from PtCl2 and AgSbF6. Etherification of benzylic alcohols is also possible by intermolecular dehydration. Both of intra- and intermolecular etherifications smoothly proceed even under an atmosphere of air.

KW - Alcohols

KW - Dehydration

KW - Diols

KW - Ethers

KW - Platinum

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ER -

Cationic platinum-catalyzed etherification by intra- and intermolecular dehydration of alcohols

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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