Characteristic features of the C-type orbital-ordered state in the simple perovskite manganite Sr1-xNdxMnO3

Hiroki Sato, Yasuhide Inoue, Yasumasa Koyama

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    In the highly-correlated electronic system Sr1-x NdxMnO3, the C-type orbital-ordered (COO) state is present for 0.15<x<0.38, and its crystal structure with the tetragonal-I4/mcm symmetry involves both the R25-type rotational displacement of MnO6 octahedra and the Jahn-Teller distortion as a response of a lattice system to orbital ordering. To understand the details of the competition between the rotational displacement and the Jahn-Teller distortion, the formation of the COO state from the disordered cubic (DC) state with the space group Pm3m has been investigated mainly by transmission electron microscopy. It was found that, when the temperature was lowered from the DC state for x = 0.20, for instance, COO regions with the tetragonal symmetry, exhibiting a {110}DC banded structure, were locally formed in the matrix below about 330 K. The subsequent aging at 300 K resulted in the growth of COO regions; that is, the time-relaxation phenomenon. Because of the presence of antiphase boundaries for the rotational displacement in the matrix, the crystal structure of the matrix should also have the tetragonal symmetry. In other words, it is understood that the coexistence state appearing just after cooling from the DC state consists of two tetragonal regions with different c/a values. The coexistence state is apparently characteristic of the competition between the rotational displacement and the Jahn-Teller distortion for the formation of the COO state.

    Original languageEnglish
    Title of host publicationAdvanced Materials Research
    PublisherTrans Tech Publications
    Pages626-631
    Number of pages6
    Volume922
    ISBN (Print)9783038350743
    DOIs
    Publication statusPublished - 2014
    Event8th International Conference on Processing and Manufacturing of Advanced Materials: Processing, Fabrication, Properties, Applications, THERMEC 2013 - Las Vegas, NV
    Duration: 2013 Dec 22013 Dec 6

    Publication series

    NameAdvanced Materials Research
    Volume922
    ISSN (Print)10226680

    Other

    Other8th International Conference on Processing and Manufacturing of Advanced Materials: Processing, Fabrication, Properties, Applications, THERMEC 2013
    CityLas Vegas, NV
    Period13/12/213/12/6

    Fingerprint

    Jahn-Teller effect
    Perovskite
    Crystal structure
    Crystal symmetry
    Crystal lattices
    Relaxation time
    Aging of materials
    Transmission electron microscopy
    Cooling
    Temperature

    Keywords

    • C-type orbital ordering
    • Simple-perovskite manganite
    • Time-relaxation phenomenon
    • Transmission electron microscopy

    ASJC Scopus subject areas

    • Engineering(all)

    Cite this

    Sato, H., Inoue, Y., & Koyama, Y. (2014). Characteristic features of the C-type orbital-ordered state in the simple perovskite manganite Sr1-xNdxMnO3 In Advanced Materials Research (Vol. 922, pp. 626-631). (Advanced Materials Research; Vol. 922). Trans Tech Publications. https://doi.org/10.4028/www.scientific.net/AMR.922.626

    Characteristic features of the C-type orbital-ordered state in the simple perovskite manganite Sr1-xNdxMnO3 . / Sato, Hiroki; Inoue, Yasuhide; Koyama, Yasumasa.

    Advanced Materials Research. Vol. 922 Trans Tech Publications, 2014. p. 626-631 (Advanced Materials Research; Vol. 922).

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Sato, H, Inoue, Y & Koyama, Y 2014, Characteristic features of the C-type orbital-ordered state in the simple perovskite manganite Sr1-xNdxMnO3 in Advanced Materials Research. vol. 922, Advanced Materials Research, vol. 922, Trans Tech Publications, pp. 626-631, 8th International Conference on Processing and Manufacturing of Advanced Materials: Processing, Fabrication, Properties, Applications, THERMEC 2013, Las Vegas, NV, 13/12/2. https://doi.org/10.4028/www.scientific.net/AMR.922.626
    Sato H, Inoue Y, Koyama Y. Characteristic features of the C-type orbital-ordered state in the simple perovskite manganite Sr1-xNdxMnO3 In Advanced Materials Research. Vol. 922. Trans Tech Publications. 2014. p. 626-631. (Advanced Materials Research). https://doi.org/10.4028/www.scientific.net/AMR.922.626
    Sato, Hiroki ; Inoue, Yasuhide ; Koyama, Yasumasa. / Characteristic features of the C-type orbital-ordered state in the simple perovskite manganite Sr1-xNdxMnO3 Advanced Materials Research. Vol. 922 Trans Tech Publications, 2014. pp. 626-631 (Advanced Materials Research).
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    abstract = "In the highly-correlated electronic system Sr1-x NdxMnO3, the C-type orbital-ordered (COO) state is present for 0.1525-type rotational displacement of MnO6 octahedra and the Jahn-Teller distortion as a response of a lattice system to orbital ordering. To understand the details of the competition between the rotational displacement and the Jahn-Teller distortion, the formation of the COO state from the disordered cubic (DC) state with the space group Pm3m has been investigated mainly by transmission electron microscopy. It was found that, when the temperature was lowered from the DC state for x = 0.20, for instance, COO regions with the tetragonal symmetry, exhibiting a {110}DC banded structure, were locally formed in the matrix below about 330 K. The subsequent aging at 300 K resulted in the growth of COO regions; that is, the time-relaxation phenomenon. Because of the presence of antiphase boundaries for the rotational displacement in the matrix, the crystal structure of the matrix should also have the tetragonal symmetry. In other words, it is understood that the coexistence state appearing just after cooling from the DC state consists of two tetragonal regions with different c/a values. The coexistence state is apparently characteristic of the competition between the rotational displacement and the Jahn-Teller distortion for the formation of the COO state.",
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