Characterization of sodium cobalt oxides related to PB-phase superconductor

Kazunori Takada, Minoru Osada, Fujio Izumi, Hiroya Sakurai, Eiji Takayama-Muromachi, Takayoshi Sasaki

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Abstract

This paper reports characterization of sodium cobalt oxides related to a PS-phase superconductor (space group R3̄m) newly found other than P2 phase (space group P63/mmc). α-NaCoO2 used as a parent compound for the synthesis of the superconductor was oxidized to be Na 0.42CoO2, in which the rhombohedral structure in the parent phase providing octahedral coordination environment for Na+ ions changed to a monoclinic lattice with trigonal prismatic sites. Hydration of the as-oxidized Na0.42CoO2 to the superconducting bilayer-hydrate phase was accompanied by the ion exchange between Na+ and H3O+ ions and reductive insertion of H 3O+ ions as observed in the formation of P2-phase superconductor. Partial dehydration of the superconducting phase transformed its bilayer-hydrate structure into a monolayer-hydrate one, in which the superconductivity disappeared again. Influence of the decreasing interlayer distance caused by the dehydration upon the guest species is discussed in combination with the results of Raman spectroscopy.

Original languageEnglish
Pages (from-to)2034-2040
Number of pages7
JournalChemistry of Materials
Volume17
Issue number8
DOIs
Publication statusPublished - 2005 Apr 19
Externally publishedYes

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ASJC Scopus subject areas

  • Materials Chemistry
  • Materials Science(all)

Cite this

Takada, K., Osada, M., Izumi, F., Sakurai, H., Takayama-Muromachi, E., & Sasaki, T. (2005). Characterization of sodium cobalt oxides related to PB-phase superconductor. Chemistry of Materials, 17(8), 2034-2040. https://doi.org/10.1021/cm047737y