Charge-transporting property of poly(l,3-phenylenevinylene) containing a nitroxide-substituted phenylamine moiety

Fumiaki Kato, Takashi Kurata, Hiroyuki Nishide, Junji Kido

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A new hole-transporting polyradical, poly(4-(N-t-butyl-N-oxyamino) triphenylamine-alt-5-hexyloxy-1,3-phenylenevinylene), was synthesized by Wittig reaction of 4-{N-i-butyl-N-(t-butyldimethylsilyl)oxy}amine-substituted bisformyltriphenylamine and l,3-bis{(triphenylphospho)methyl}benzene dibromide, followed by deprotection and oxidation. Electrochemical or magnetic measurements revealed the electronic structure and charge transporting property of the polyradical.

Original languageEnglish
Title of host publicationPolymer Preprints, Japan
Pages4107
Number of pages1
Volume54
Edition2
Publication statusPublished - 2005
Event54th SPSJ Symposium on Macromolecules - Yamagata
Duration: 2005 Sep 202005 Sep 22

Other

Other54th SPSJ Symposium on Macromolecules
CityYamagata
Period05/9/2005/9/22

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Keywords

  • Nitroxide
  • PolyradicalRedox property
  • Wittig reaction

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Kato, F., Kurata, T., Nishide, H., & Kido, J. (2005). Charge-transporting property of poly(l,3-phenylenevinylene) containing a nitroxide-substituted phenylamine moiety. In Polymer Preprints, Japan (2 ed., Vol. 54, pp. 4107)