Chemical Design of Palladium-Based Nanoarchitectures for Catalytic Applications

Muhammad Iqbal, Yusuf Valentino Kaneti, Jeonghun Kim, Brian Yuliarto, Yong Mook Kang, Yoshio Bando, Yoshiyuki Sugahara, Yusuke Yamauchi

Research output: Contribution to journalArticle

Abstract

Palladium (Pd) plays an important role in numerous catalytic reactions, such as methanol and ethanol oxidation, oxygen reduction, hydrogenation, coupling reactions, and carbon monoxide oxidation. Creating Pd-based nanoarchitectures with increased active surface sites, higher density of low-coordinated atoms, and maximized surface coverage for the reactants is important. To address the limitations of pure Pd, various Pd-based nanoarchitectures, including alloys, intermetallics, and supported Pd nanomaterials, have been fabricated by combining Pd with other elements with similar or higher catalytic activity for many catalytic reactions. Herein, recent advances in the preparation of Pd-based nanoarchitectures through solution-phase chemical reduction and electrochemical deposition methods are summarized. Finally, the trend and future outlook in the development of Pd nanocatalysts toward practical catalytic applications are discussed.

LanguageEnglish
Article number1804378
JournalSmall
DOIs
Publication statusAccepted/In press - 2019 Jan 1

Fingerprint

Palladium
Oxidation
Hydrogenation
Nanostructures
Carbon Monoxide
Nanostructured materials
Carbon monoxide
Intermetallics
Methanol
Catalyst activity
Catalytic Domain
Ethanol
Oxygen
Atoms

Keywords

  • alloys
  • catalysis
  • electrochemical deposition
  • intermetallic structures
  • palladium nanoarchitectures

ASJC Scopus subject areas

  • Biotechnology
  • Biomaterials
  • Chemistry(all)
  • Materials Science(all)

Cite this

Iqbal, M., Kaneti, Y. V., Kim, J., Yuliarto, B., Kang, Y. M., Bando, Y., ... Yamauchi, Y. (Accepted/In press). Chemical Design of Palladium-Based Nanoarchitectures for Catalytic Applications. Small, [1804378]. https://doi.org/10.1002/smll.201804378

Chemical Design of Palladium-Based Nanoarchitectures for Catalytic Applications. / Iqbal, Muhammad; Kaneti, Yusuf Valentino; Kim, Jeonghun; Yuliarto, Brian; Kang, Yong Mook; Bando, Yoshio; Sugahara, Yoshiyuki; Yamauchi, Yusuke.

In: Small, 01.01.2019.

Research output: Contribution to journalArticle

Iqbal M, Kaneti YV, Kim J, Yuliarto B, Kang YM, Bando Y et al. Chemical Design of Palladium-Based Nanoarchitectures for Catalytic Applications. Small. 2019 Jan 1. 1804378. https://doi.org/10.1002/smll.201804378
Iqbal, Muhammad ; Kaneti, Yusuf Valentino ; Kim, Jeonghun ; Yuliarto, Brian ; Kang, Yong Mook ; Bando, Yoshio ; Sugahara, Yoshiyuki ; Yamauchi, Yusuke. / Chemical Design of Palladium-Based Nanoarchitectures for Catalytic Applications. In: Small. 2019.
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