Chemoselective and regiospecific suzuki coupling on a multisubstituted sp3-Carbon in 1,1-diborylalkanes at room temperature

Kohei Endo, Takahiro Ohkubo, Munenao Hirokami, Takanori Shibata

Research output: Contribution to journalArticlepeer-review

135 Citations (Scopus)

Abstract

The palladium-catalyzed Suzuki-Miyaura cross-coupling on a multisubstituted sp3-carbon in 1,1-diborylalkanes was achieved at room temperature. The generation of a monoborate intermediate by virtue of the adjacent B atom could result in the chemoselective coupling reaction under ambient conditions.

Original languageEnglish
Pages (from-to)11033-11035
Number of pages3
JournalJournal of the American Chemical Society
Volume132
Issue number32
DOIs
Publication statusPublished - 2010 Aug 18

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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