Abstract
Herein we developed a new approach of creating topologically and well-defined patterned polymeric surfaces via the "grafting to" approach. This was accomplished by either using colloidally templated "clickable" arrays, whereby the chemistry was performed directly onto the pattern or by subsequent backfilling with azido terminated SAM's. Similarly, direct grafting of electroactive temperature responsive oligo(ethylene glycol) methacrylic polymers to colloidally templated surfaces allowed for tunable ion gate formation.
| Original language | English |
|---|---|
| Pages (from-to) | 3124-3134 |
| Number of pages | 11 |
| Journal | Polymer (United Kingdom) |
| Volume | 53 |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - 2012 Jul 6 |
| Externally published | Yes |
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Keywords
- Colloidal templating
- Electrodeposition
- Ion gate
ASJC Scopus subject areas
- Organic Chemistry
- Polymers and Plastics
Cite this
Click chemistry and electro-grafting onto colloidally templated conducting polymer arrays. / Foster, Edward L.; Bunha, Ajaykumar; Advincula, Rigoberto.
In: Polymer (United Kingdom), Vol. 53, No. 15, 06.07.2012, p. 3124-3134.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Click chemistry and electro-grafting onto colloidally templated conducting polymer arrays
AU - Foster, Edward L.
AU - Bunha, Ajaykumar
AU - Advincula, Rigoberto
PY - 2012/7/6
Y1 - 2012/7/6
N2 - Herein we developed a new approach of creating topologically and well-defined patterned polymeric surfaces via the "grafting to" approach. This was accomplished by either using colloidally templated "clickable" arrays, whereby the chemistry was performed directly onto the pattern or by subsequent backfilling with azido terminated SAM's. Similarly, direct grafting of electroactive temperature responsive oligo(ethylene glycol) methacrylic polymers to colloidally templated surfaces allowed for tunable ion gate formation.
AB - Herein we developed a new approach of creating topologically and well-defined patterned polymeric surfaces via the "grafting to" approach. This was accomplished by either using colloidally templated "clickable" arrays, whereby the chemistry was performed directly onto the pattern or by subsequent backfilling with azido terminated SAM's. Similarly, direct grafting of electroactive temperature responsive oligo(ethylene glycol) methacrylic polymers to colloidally templated surfaces allowed for tunable ion gate formation.
KW - Colloidal templating
KW - Electrodeposition
KW - Ion gate
UR - http://www.scopus.com/inward/record.url?scp=84862758705&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84862758705&partnerID=8YFLogxK
U2 - 10.1016/j.polymer.2012.05.040
DO - 10.1016/j.polymer.2012.05.040
M3 - Article
VL - 53
SP - 3124
EP - 3134
JO - Polymer (United Kingdom)
JF - Polymer (United Kingdom)
SN - 0032-3861
IS - 15
ER -