Collective motion in Poly(ethylene oxide)/poly(methylmethacrylate) blends

Bela Farago, Chunxia Chen, Janna K. Maranas, Sudesh Kamath, Ralph H. Colby, Anthony J. Pasquale, Timothy Edward Long

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

We present neutron spin echo and structural measurements on a perdeutereted miscible polymer blend: poly(ethylene oxide)[PEO]/poly(methyl methacrylate)[PMMA], characterized by a large difference in component glass transition temperatures and minimal interactions. The measurements cover the q range 0.35 to 1.66-1 and the temperature range Tg-75 to Tg+89K, where Tg is the blend glass transition. The spectra, obtained directly in the time domain, are very broad with stretching parameters β∼0.30. The relaxation times vary considerably over the spatial range considered however at none of the q values do we see two distinct relaxation times. At small spatial scales relaxations are still detectable at temperatures far below Tg. The temperature dependence of these relaxation times strongly resembles the β-relaxation process observed in pure PMMA.

Original languageEnglish
Article number031809
JournalPhysical Review E - Statistical, Nonlinear, and Soft Matter Physics
Volume72
Issue number3
DOIs
Publication statusPublished - 2005 Sep 1
Externally publishedYes

Fingerprint

Collective Motion
Ethylene
ethylene oxide
Relaxation Time
Oxides
relaxation time
Glass Transition
polymethyl methacrylate
Range of data
Polymer Blends
polymer blends
Temperature Dependence
Neutron
glass transition temperature
Time Domain
echoes
Vary
Cover
Distinct
neutrons

ASJC Scopus subject areas

  • Statistical and Nonlinear Physics
  • Statistics and Probability
  • Condensed Matter Physics

Cite this

Farago, B., Chen, C., Maranas, J. K., Kamath, S., Colby, R. H., Pasquale, A. J., & Long, T. E. (2005). Collective motion in Poly(ethylene oxide)/poly(methylmethacrylate) blends. Physical Review E - Statistical, Nonlinear, and Soft Matter Physics, 72(3), [031809]. https://doi.org/10.1103/PhysRevE.72.031809

Collective motion in Poly(ethylene oxide)/poly(methylmethacrylate) blends. / Farago, Bela; Chen, Chunxia; Maranas, Janna K.; Kamath, Sudesh; Colby, Ralph H.; Pasquale, Anthony J.; Long, Timothy Edward.

In: Physical Review E - Statistical, Nonlinear, and Soft Matter Physics, Vol. 72, No. 3, 031809, 01.09.2005.

Research output: Contribution to journalArticle

Farago, Bela ; Chen, Chunxia ; Maranas, Janna K. ; Kamath, Sudesh ; Colby, Ralph H. ; Pasquale, Anthony J. ; Long, Timothy Edward. / Collective motion in Poly(ethylene oxide)/poly(methylmethacrylate) blends. In: Physical Review E - Statistical, Nonlinear, and Soft Matter Physics. 2005 ; Vol. 72, No. 3.
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