Comparison of the extractabilities of tetrachloro- and tetrabromopalladate(II) ions with a thiodiglycolamide compound

Hirokazu Narita, Motoki Maeda, Chiharu Tokoro, Tomoya Suzuki, Mikiya Tanaka, Ryuhei Motokawa, Hideaki Shiwaku, Tsuyoshi Yaita

    Research output: Contribution to journalArticle

    3 Citations (Scopus)

    Abstract

    Using N,N,N',N'-tetra-2-ethylhexyl-thiodiglycolamide (TEHTDGA) in n-dodecane as the extractant, we compared the percentages of Pd(II) extracted from HCl and HBr solutions, and analyzed the structures of the Pd(II)-extractant complexes. For comparison, similar experiments were performed with di-n-hexyl sulfide (DHS), a well-known sulfide-type extractant. TEHTDGA extracted Pd(II) from both HCl and HBr solutions much faster than DHS. The Pd(II)/(TEHTDGA or DHS) stoichiometry in the organic phase was 1:2. For TEHTDGA, the extractability of Pd(II) from HBr solution was inferior to that from HCl solution, whereas the opposite was true for DHS. However, FT-IR spectroscopy and EXAFS measurements indicated that the inner-sphere structure of Pd(II) in the TEHTDGA complex was almost the same as that in the DHS system: in both cases, two of the halide ions in the tetrachloro- or tetrabromopalladate(II) ion were replaced by the sulfur atoms of two extractant molecules.

    Original languageEnglish
    Pages (from-to)1305-1309
    Number of pages5
    JournalAnalytical Sciences
    Volume33
    Issue number11
    DOIs
    Publication statusPublished - 2017

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    Sulfides
    Ions
    Sulfur
    Stoichiometry
    Infrared spectroscopy
    Atoms
    Molecules
    Experiments

    Keywords

    • HBr
    • HCl
    • Liquid-liquid extraction
    • Palladium
    • Thiodiglycolamide

    ASJC Scopus subject areas

    • Analytical Chemistry

    Cite this

    Comparison of the extractabilities of tetrachloro- and tetrabromopalladate(II) ions with a thiodiglycolamide compound. / Narita, Hirokazu; Maeda, Motoki; Tokoro, Chiharu; Suzuki, Tomoya; Tanaka, Mikiya; Motokawa, Ryuhei; Shiwaku, Hideaki; Yaita, Tsuyoshi.

    In: Analytical Sciences, Vol. 33, No. 11, 2017, p. 1305-1309.

    Research output: Contribution to journalArticle

    Narita, Hirokazu ; Maeda, Motoki ; Tokoro, Chiharu ; Suzuki, Tomoya ; Tanaka, Mikiya ; Motokawa, Ryuhei ; Shiwaku, Hideaki ; Yaita, Tsuyoshi. / Comparison of the extractabilities of tetrachloro- and tetrabromopalladate(II) ions with a thiodiglycolamide compound. In: Analytical Sciences. 2017 ; Vol. 33, No. 11. pp. 1305-1309.
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    AU - Suzuki, Tomoya

    AU - Tanaka, Mikiya

    AU - Motokawa, Ryuhei

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