Conducting polymer alloys for photo-enhanced electro-catalytic oxygen reduction

Bartlomiej Kolodziejczyk, Orawan Winther-Jensen, Douglas R. MacFarlane, Bjorn Winther Jensen

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Electro-catalysis is a core element in many technologies proposed for energy storage and conversion in a post-petroleum energy landscape. This has prompted the development of new electro-catalysts, for example for fuel-cells, water-splitting cells, and metal-air batteries, which are not based on traditional rare metals such as platinum, palladium and iridium. In this context, the possibility to use organic conjugated polymers to replace inorganic catalysts has shown promising progress. We hereby demonstrate that an "alloy" of two conjugated polymers, poly[3,4-ethylenedioxythiophene] and polythiophenes, with different oxidation states can act as a photo-enhanced reduction catalyst for the oxygen reduction reaction and thereby reduce the overpotential for that reaction by more than 600 mV under illumination.

Original languageEnglish
Pages (from-to)10821-10826
Number of pages6
JournalJournal of Materials Chemistry
Volume22
Issue number21
DOIs
Publication statusPublished - 2012 Jun 7
Externally publishedYes

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Conducting polymers
Conjugated polymers
Oxygen
Catalysts
Metals
Iridium
Organic polymers
Petroleum
Palladium
Platinum
Energy conversion
Chemical elements
Energy storage
Catalysis
Fuel cells
Crude oil
Lighting
Oxidation
Water
Polymers

ASJC Scopus subject areas

  • Materials Chemistry
  • Chemistry(all)

Cite this

Conducting polymer alloys for photo-enhanced electro-catalytic oxygen reduction. / Kolodziejczyk, Bartlomiej; Winther-Jensen, Orawan; MacFarlane, Douglas R.; Winther Jensen, Bjorn.

In: Journal of Materials Chemistry, Vol. 22, No. 21, 07.06.2012, p. 10821-10826.

Research output: Contribution to journalArticle

Kolodziejczyk, Bartlomiej ; Winther-Jensen, Orawan ; MacFarlane, Douglas R. ; Winther Jensen, Bjorn. / Conducting polymer alloys for photo-enhanced electro-catalytic oxygen reduction. In: Journal of Materials Chemistry. 2012 ; Vol. 22, No. 21. pp. 10821-10826.
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