Controlled growth for synthesizing a compact mordenite membrane

Masahiko Matsukata, Ken ichi Sawamura, Tsutomu Shirai, Mitsuko Takada, Yasushi Sekine, Eiichi Kikuchi

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    26 Citations (Scopus)

    Abstract

    Controlling the growth of zeolite crystals on a porous alumina support is essential for preparing a compact zeolite membarne. First, mordenite seed crystals applied on a nonporous α-alumina disk were grown and morphological change of mordenite crystals were observed in the course of growth. Then, mordenite membranes were synthesized on a porous α-alumina tube under the same conditions employed in the study using the alumina disks. We found that seed crystal growth was widely controllable by changing water content in reaction solution, which resulted in better control of the morphology of mordenite crystals for synthesizing a thin compact mordenite membrane. Separation properties for mordenite membranes were studied in water-hydrogen binary system at 473 K with 10 kPa of water partial pressure, where no capillary condensation was expected in non-zeolitic pores. Separation factor for a mordenite membrane with a few defects was poor; however, a defect-free mordenite membrane prepared under a suitable condition highly separated steam from hydrogen.

    Original languageEnglish
    Pages (from-to)18-27
    Number of pages10
    JournalJournal of Membrane Science
    Volume316
    Issue number1-2
    DOIs
    Publication statusPublished - 2008 May 15

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    Keywords

    • Mordenite
    • Secondary growth
    • Separation
    • Synthesis
    • Zeolite membrane

    ASJC Scopus subject areas

    • Filtration and Separation
    • Polymers and Plastics

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