Controlling the rate of water-induced switching in mechanically dynamic cellulose nanocrystal composites

Koffi L. Dagnon, Amanda E. Way, Sidney O. Carson, Jorge Silva, Joao Maia, Stuart J. Rowan

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Carboxylated cellulose nanocrystals with varying charge densities, ranging from ca. 270 to -1100 mmol/kg, were prepared via partial functionalization of 1100 mmol/kg carboxylated CNCs with different equivalents of propylamine. Incorporation of these differently charged nanofillers into poly(vinyl acetate) produced a series of water-responsive mechanically adaptable nanocomposite materials. Dynamic mechanical analysis and rheological studies of the nanocomposite samples indicated that both the degree of water swelling and the rate of mechanical softening are related to the CNC charge density. Interestingly, however, the mechanical properties of the nanocomposites, either dry or fully swollen, are more-or-less independent of the charge density of the CNC nanofillers. Thus, these results highlight a method to tailor the rate of mechanical switching (or diffusion of water through the nanocomposite material) without significantly impacting its mechanical properties.

Original languageEnglish
Pages (from-to)8203-8212
Number of pages10
JournalMacromolecules
Volume46
Issue number20
DOIs
Publication statusPublished - 2013
Externally publishedYes

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Cellulose
Nanocrystals
Nanocomposites
Charge density
Water
Composite materials
Propylamines
Mechanical properties
Dynamic mechanical analysis
Swelling

ASJC Scopus subject areas

  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry

Cite this

Dagnon, K. L., Way, A. E., Carson, S. O., Silva, J., Maia, J., & Rowan, S. J. (2013). Controlling the rate of water-induced switching in mechanically dynamic cellulose nanocrystal composites. Macromolecules, 46(20), 8203-8212. https://doi.org/10.1021/ma4008187

Controlling the rate of water-induced switching in mechanically dynamic cellulose nanocrystal composites. / Dagnon, Koffi L.; Way, Amanda E.; Carson, Sidney O.; Silva, Jorge; Maia, Joao; Rowan, Stuart J.

In: Macromolecules, Vol. 46, No. 20, 2013, p. 8203-8212.

Research output: Contribution to journalArticle

Dagnon, KL, Way, AE, Carson, SO, Silva, J, Maia, J & Rowan, SJ 2013, 'Controlling the rate of water-induced switching in mechanically dynamic cellulose nanocrystal composites', Macromolecules, vol. 46, no. 20, pp. 8203-8212. https://doi.org/10.1021/ma4008187
Dagnon, Koffi L. ; Way, Amanda E. ; Carson, Sidney O. ; Silva, Jorge ; Maia, Joao ; Rowan, Stuart J. / Controlling the rate of water-induced switching in mechanically dynamic cellulose nanocrystal composites. In: Macromolecules. 2013 ; Vol. 46, No. 20. pp. 8203-8212.
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