Conversion of an Aurivillius phase Bi 2SrNaNb 3O 12 into its protonated form via treatment with various mineral acids

Masashi Shirata, Yu Tsunoda, Wataru Sugimoto, Yoshiyuki Sugahara

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    5 Citations (Scopus)

    Abstract

    A protonated form of a layered perovskite was prepared from an Aurivillius phase Bi 2SrNaNb 3O 12 via acid treatments, and the effect of the type of mineral acids was investigated. The treatment with HX (X = Cl, Br, I) resulted in the formation of a protonated form H 1.8[Sr 0.8Bi 0.2NaNb 3O 10], while no reactions were observed for HNO 3 and H 2SO 4 under the present experimental conditions. All the products obtained by HX-treatments exhibited layered structures and the structures of the perovskite-like slabs were preserved.

    Original languageEnglish
    Title of host publicationMaterials Research Society Symposium - Proceedings
    EditorsM Geselbracht, J Greedan, D Johnson, M A Subramanian
    Volume658
    Publication statusPublished - 2001
    EventSolid - State Chemistry of Inorganic Materials III - Boston, MA, United States
    Duration: 2000 Nov 272000 Nov 30

    Other

    OtherSolid - State Chemistry of Inorganic Materials III
    CountryUnited States
    CityBoston, MA
    Period00/11/2700/11/30

    Fingerprint

    Perovskite
    Minerals
    Acids
    perovskite

    ASJC Scopus subject areas

    • Electronic, Optical and Magnetic Materials

    Cite this

    Shirata, M., Tsunoda, Y., Sugimoto, W., & Sugahara, Y. (2001). Conversion of an Aurivillius phase Bi 2SrNaNb 3O 12 into its protonated form via treatment with various mineral acids In M. Geselbracht, J. Greedan, D. Johnson, & M. A. Subramanian (Eds.), Materials Research Society Symposium - Proceedings (Vol. 658)

    Conversion of an Aurivillius phase Bi 2SrNaNb 3O 12 into its protonated form via treatment with various mineral acids . / Shirata, Masashi; Tsunoda, Yu; Sugimoto, Wataru; Sugahara, Yoshiyuki.

    Materials Research Society Symposium - Proceedings. ed. / M Geselbracht; J Greedan; D Johnson; M A Subramanian. Vol. 658 2001.

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Shirata, M, Tsunoda, Y, Sugimoto, W & Sugahara, Y 2001, Conversion of an Aurivillius phase Bi 2SrNaNb 3O 12 into its protonated form via treatment with various mineral acids in M Geselbracht, J Greedan, D Johnson & MA Subramanian (eds), Materials Research Society Symposium - Proceedings. vol. 658, Solid - State Chemistry of Inorganic Materials III, Boston, MA, United States, 00/11/27.
    Shirata M, Tsunoda Y, Sugimoto W, Sugahara Y. Conversion of an Aurivillius phase Bi 2SrNaNb 3O 12 into its protonated form via treatment with various mineral acids In Geselbracht M, Greedan J, Johnson D, Subramanian MA, editors, Materials Research Society Symposium - Proceedings. Vol. 658. 2001
    Shirata, Masashi ; Tsunoda, Yu ; Sugimoto, Wataru ; Sugahara, Yoshiyuki. / Conversion of an Aurivillius phase Bi 2SrNaNb 3O 12 into its protonated form via treatment with various mineral acids Materials Research Society Symposium - Proceedings. editor / M Geselbracht ; J Greedan ; D Johnson ; M A Subramanian. Vol. 658 2001.
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    AB - A protonated form of a layered perovskite was prepared from an Aurivillius phase Bi 2SrNaNb 3O 12 via acid treatments, and the effect of the type of mineral acids was investigated. The treatment with HX (X = Cl, Br, I) resulted in the formation of a protonated form H 1.8[Sr 0.8Bi 0.2NaNb 3O 10], while no reactions were observed for HNO 3 and H 2SO 4 under the present experimental conditions. All the products obtained by HX-treatments exhibited layered structures and the structures of the perovskite-like slabs were preserved.

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