Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal-Metal Bond

Tadashi Yamaguchi, Kohei Yoshiya

Research output: Contribution to journalArticle

Abstract

New type isomers that differ in metal-metal bond type are isolated. One is the Pt-Hg-Pt complex, which has two metal-metal covalent bonds, Pt-Hg = 2.5459(8) and 2.5483(7) Å, and the other is the Pt→Hg-Pt complex, which has one metal-metal covalent bond, Pt-Hg = 2.5744(6) Å, and one metal-metal dative bond, Pt→Hg = 2.6635(7) Å.

Original languageEnglish
Pages (from-to)9548-9552
Number of pages5
JournalInorganic Chemistry
Volume58
Issue number15
DOIs
Publication statusPublished - 2019 Aug 5

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Isomers
isomers
Metals
metals
Covalent bonds
covalent bonds

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal-Metal Bond. / Yamaguchi, Tadashi; Yoshiya, Kohei.

In: Inorganic Chemistry, Vol. 58, No. 15, 05.08.2019, p. 9548-9552.

Research output: Contribution to journalArticle

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abstract = "New type isomers that differ in metal-metal bond type are isolated. One is the Pt-Hg-Pt complex, which has two metal-metal covalent bonds, Pt-Hg = 2.5459(8) and 2.5483(7) {\AA}, and the other is the Pt→Hg-Pt complex, which has one metal-metal covalent bond, Pt-Hg = 2.5744(6) {\AA}, and one metal-metal dative bond, Pt→Hg = 2.6635(7) {\AA}.",
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