Coordination structure and magnetic property of poly(pyridilenemethylidenenitriloiron)s

Hiroyuki Nishide, Naoki Yoshioka, Eishun Tsuchida, Hidenari Inoue

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Poly[bis(2,6-pyridinediylmethylidenenitrilohexamethylidene)iron sulfate] was said to be a ferromagnetic compound by earlier investigators. This polymer and its derivatives are carefully reprepared and their unusual magnetic property is reinvestigated spectroscopically. The counter anion species and spacer length of the polymers affect their coordination structure and magnetism. Mossbauer spectroscopy and x-ray diffractometry on the polymers indicate that their unusual magnetic property is caused by the ferromagnetic iron oxide slightly formed in the polymers.

Original languageEnglish
Pages (from-to)497-505
Number of pages9
JournalJournal of Polymer Science, Part A: Polymer Chemistry
Volume27
Issue number2
DOIs
Publication statusPublished - 1989

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

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