Copper(II) complexes resulting from the oxygenation of (2,9-dimethyl-1,10-phenanthroline)copper(I) chloride in the presence of dimethylformamide

Kenichi Oyaizu, M. Ueno, H. Li, E. Tsuchida

    Research output: Contribution to journalArticle

    5 Citations (Scopus)

    Abstract

    The oxygenation of (2,9-dimethyl-1,10-phenanthroline) copper(I) chloride in THF, followed by a treatment with DMF and acidification with HCl, afforded dichloro[2-(dimethylamino) (hydroxy)methyl-9-methyl-1,10-phenanthroline] copper(II) and (aqua)dichloro(2,9-dimethyl-1,10-phenanthroline) copper(II) quantitatively.

    Original languageEnglish
    Pages (from-to)869-870
    Number of pages2
    JournalBulletin of the Chemical Society of Japan
    Volume74
    Issue number5
    DOIs
    Publication statusPublished - 2001 May

    Fingerprint

    Dimethylformamide
    Oxygenation
    Copper
    Acidification
    cuprous chloride
    neocuproine
    copper-1,10-phenanthroline

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    @article{71b045a872324ffd99d184593caa8e2f,
    title = "Copper(II) complexes resulting from the oxygenation of (2,9-dimethyl-1,10-phenanthroline)copper(I) chloride in the presence of dimethylformamide",
    abstract = "The oxygenation of (2,9-dimethyl-1,10-phenanthroline) copper(I) chloride in THF, followed by a treatment with DMF and acidification with HCl, afforded dichloro[2-(dimethylamino) (hydroxy)methyl-9-methyl-1,10-phenanthroline] copper(II) and (aqua)dichloro(2,9-dimethyl-1,10-phenanthroline) copper(II) quantitatively.",
    author = "Kenichi Oyaizu and M. Ueno and H. Li and E. Tsuchida",
    year = "2001",
    month = "5",
    doi = "10.1246/bcsj.74.869",
    language = "English",
    volume = "74",
    pages = "869--870",
    journal = "Bulletin of the Chemical Society of Japan",
    issn = "0009-2673",
    publisher = "Chemical Society of Japan",
    number = "5",

    }

    TY - JOUR

    T1 - Copper(II) complexes resulting from the oxygenation of (2,9-dimethyl-1,10-phenanthroline)copper(I) chloride in the presence of dimethylformamide

    AU - Oyaizu, Kenichi

    AU - Ueno, M.

    AU - Li, H.

    AU - Tsuchida, E.

    PY - 2001/5

    Y1 - 2001/5

    N2 - The oxygenation of (2,9-dimethyl-1,10-phenanthroline) copper(I) chloride in THF, followed by a treatment with DMF and acidification with HCl, afforded dichloro[2-(dimethylamino) (hydroxy)methyl-9-methyl-1,10-phenanthroline] copper(II) and (aqua)dichloro(2,9-dimethyl-1,10-phenanthroline) copper(II) quantitatively.

    AB - The oxygenation of (2,9-dimethyl-1,10-phenanthroline) copper(I) chloride in THF, followed by a treatment with DMF and acidification with HCl, afforded dichloro[2-(dimethylamino) (hydroxy)methyl-9-methyl-1,10-phenanthroline] copper(II) and (aqua)dichloro(2,9-dimethyl-1,10-phenanthroline) copper(II) quantitatively.

    UR - http://www.scopus.com/inward/record.url?scp=0034962845&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=0034962845&partnerID=8YFLogxK

    U2 - 10.1246/bcsj.74.869

    DO - 10.1246/bcsj.74.869

    M3 - Article

    VL - 74

    SP - 869

    EP - 870

    JO - Bulletin of the Chemical Society of Japan

    JF - Bulletin of the Chemical Society of Japan

    SN - 0009-2673

    IS - 5

    ER -