Corrosion behavior of a duplex stainless steel in a simulated crevice solution

So Aoki, Reisuke Doi, Kiyotaka Ito, Jun'ichi Sakai, Hiroshi Yakuwa, Katsuhiro Mitsuhashi

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    The repassivation potential of corroding crevices of a duplex stainless steel was measured in a deaerated 3.5mass% NaCl solution according to JIS G 0592. The change of current density with time and preferential dissolution phase during anodic polarization in -370mV to +150mV (vs. SCE) potential region in a simulated crevice solution (25mass% NaCl, pH 0) were investigated. The repassivation potential of crevice corrosion depended on the holding potential and time for ensuring the propagation of crevice corrosion, and in all the cases, the preferential dissolution of ferritic phase was observed. The current density was rather steady during the potentiostatic measurement in the active peak region (-370mV to -260mV). While, it decreased with time in the active-passive transition region (-200mV to -150mV). In the passive region (0mV to +150mV), it first decreased, and then increased gradually. On the less-noble side of the active peak region, preferential dissolution occurred on the ferritic phase. On the other hand, on the noble side of the active peak region and in the active-passive transition region, it occurred on the austenitic phase. In the passive region, both phases dissolved evenly. These results suggest that the potential in the corroding crevice drops to the less-noble side of the active peak region by the IR drop mechanism.

    Original languageEnglish
    Title of host publication17th International Corrosion Congress 2008: Corrosion Control in the Service of Society
    Pages927-935
    Number of pages9
    Volume2
    Publication statusPublished - 2008
    Event17th International Corrosion Congress 2008: Corrosion Control in the Service of Society - Las Vegas, NV
    Duration: 2008 Oct 62008 Oct 10

    Other

    Other17th International Corrosion Congress 2008: Corrosion Control in the Service of Society
    CityLas Vegas, NV
    Period08/10/608/10/10

    Fingerprint

    Stainless Steel
    Dissolution
    Stainless steel
    Corrosion
    Current density
    Anodic polarization

    Keywords

    • Crevice corrosion
    • Duplex stainless steel
    • IR drop
    • Preferential dissolution
    • Repassivation potential

    ASJC Scopus subject areas

    • Colloid and Surface Chemistry
    • Surfaces, Coatings and Films

    Cite this

    Aoki, S., Doi, R., Ito, K., Sakai, J., Yakuwa, H., & Mitsuhashi, K. (2008). Corrosion behavior of a duplex stainless steel in a simulated crevice solution. In 17th International Corrosion Congress 2008: Corrosion Control in the Service of Society (Vol. 2, pp. 927-935)

    Corrosion behavior of a duplex stainless steel in a simulated crevice solution. / Aoki, So; Doi, Reisuke; Ito, Kiyotaka; Sakai, Jun'ichi; Yakuwa, Hiroshi; Mitsuhashi, Katsuhiro.

    17th International Corrosion Congress 2008: Corrosion Control in the Service of Society. Vol. 2 2008. p. 927-935.

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Aoki, S, Doi, R, Ito, K, Sakai, J, Yakuwa, H & Mitsuhashi, K 2008, Corrosion behavior of a duplex stainless steel in a simulated crevice solution. in 17th International Corrosion Congress 2008: Corrosion Control in the Service of Society. vol. 2, pp. 927-935, 17th International Corrosion Congress 2008: Corrosion Control in the Service of Society, Las Vegas, NV, 08/10/6.
    Aoki S, Doi R, Ito K, Sakai J, Yakuwa H, Mitsuhashi K. Corrosion behavior of a duplex stainless steel in a simulated crevice solution. In 17th International Corrosion Congress 2008: Corrosion Control in the Service of Society. Vol. 2. 2008. p. 927-935
    Aoki, So ; Doi, Reisuke ; Ito, Kiyotaka ; Sakai, Jun'ichi ; Yakuwa, Hiroshi ; Mitsuhashi, Katsuhiro. / Corrosion behavior of a duplex stainless steel in a simulated crevice solution. 17th International Corrosion Congress 2008: Corrosion Control in the Service of Society. Vol. 2 2008. pp. 927-935
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    abstract = "The repassivation potential of corroding crevices of a duplex stainless steel was measured in a deaerated 3.5mass{\%} NaCl solution according to JIS G 0592. The change of current density with time and preferential dissolution phase during anodic polarization in -370mV to +150mV (vs. SCE) potential region in a simulated crevice solution (25mass{\%} NaCl, pH 0) were investigated. The repassivation potential of crevice corrosion depended on the holding potential and time for ensuring the propagation of crevice corrosion, and in all the cases, the preferential dissolution of ferritic phase was observed. The current density was rather steady during the potentiostatic measurement in the active peak region (-370mV to -260mV). While, it decreased with time in the active-passive transition region (-200mV to -150mV). In the passive region (0mV to +150mV), it first decreased, and then increased gradually. On the less-noble side of the active peak region, preferential dissolution occurred on the ferritic phase. On the other hand, on the noble side of the active peak region and in the active-passive transition region, it occurred on the austenitic phase. In the passive region, both phases dissolved evenly. These results suggest that the potential in the corroding crevice drops to the less-noble side of the active peak region by the IR drop mechanism.",
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    AU - Mitsuhashi, Katsuhiro

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