Cr3+ impurities and photoluminescence in LaAlO3

Eiji Hirata, Kenta Tamagawa, Yoshimichi Ohki

    Research output: Contribution to journalArticle

    17 Citations (Scopus)

    Abstract

    Photoluminescence (PL) spectra induced in LaAlO3 by ultraviolet (UV) photons were measured for two types of samples, i.e., single-crystal plates and thin films. The films, which were amorphous when deposited, became polycrystalline after being annealed at 800°C or higher. When the excitation photon energy exceeded the band-gap energy of LaAlO3, three PL peaks appeared at approximately 1.60 eV in the single crystals and polycrystalline films deposited and annealed on a Si single-crystal substrate. When the films were deposited and annealed on a CaF2 singlecrystal substrate, the in-plane lattice parameters became smaller and the energies of the three PL peaks shifted to higher values. This indicates that the three PL peaks are susceptible to a crystal field. Furthermore, the intensities of the three PL peaks did not depend on the measurement temperature. Taking these results together with their spectral shapes into consideration, the three PL peaks are due to the R-line luminescence resulting from Cr3+ impurities in LaAlO3. The detection of Cr3+ ions by inductively coupled plasma optical emission spectrometry failed, indicating that the Cr3+ content of the present samples is below 1 ppm. The fact that the PL peaks appeared in both the single-crystal plates and thin films obtained from different raw chemicals with different processes indicates that there is a strong possibility that the Cr3+ ions are present in Al ore. Another PL peak appearing at 2.8eV in the single crystals was assumed to originate from oxygen vacancies.

    Original languageEnglish
    Article number091102
    JournalJapanese Journal of Applied Physics
    Volume49
    Issue number9 PART 1
    DOIs
    Publication statusPublished - 2010 Sep

    Fingerprint

    Photoluminescence
    Impurities
    photoluminescence
    impurities
    Single crystals
    single crystals
    Photons
    Thin films
    Ions
    photons
    Inductively coupled plasma
    Substrates
    Oxygen vacancies
    thin films
    Temperature measurement
    Spectrometry
    Ores
    Lattice constants
    crystal field theory
    light emission

    ASJC Scopus subject areas

    • Engineering(all)
    • Physics and Astronomy(all)

    Cite this

    Cr3+ impurities and photoluminescence in LaAlO3 . / Hirata, Eiji; Tamagawa, Kenta; Ohki, Yoshimichi.

    In: Japanese Journal of Applied Physics, Vol. 49, No. 9 PART 1, 091102, 09.2010.

    Research output: Contribution to journalArticle

    Hirata, Eiji ; Tamagawa, Kenta ; Ohki, Yoshimichi. / Cr3+ impurities and photoluminescence in LaAlO3 In: Japanese Journal of Applied Physics. 2010 ; Vol. 49, No. 9 PART 1.
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