Crystal structure and physical properties of BEDT-TTF (bis(ethylenedithio) tetrathiafulvalene) salt coupled with a photo-sensitive transition metal complex

Masashi Ohkubo, Tokutaro Komatsu, Nobuyuki Matsushita, Norimichi Kojima, Gunzi Saito

Research output: Contribution to journalConference articlepeer-review

1 Citation (Scopus)

Abstract

A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl5(NO)]2- has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF+ and NO exhibited a photo-induced effect.

Original languageEnglish
Pages (from-to)147-152
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume376
DOIs
Publication statusPublished - 2002
Externally publishedYes
EventProceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States
Duration: 2000 Dec 152000 Dec 18

Keywords

  • BEDT-TTF
  • Organic conductors
  • Photo-induced effect

ASJC Scopus subject areas

  • Condensed Matter Physics

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