Crystal Structure and Physical Properties of BEDT-TTF (bis(ethylenedithio)tetrathiafulvalene) Salt Coupled with a Photo-Sensitive Transition Metal Complex

Masashi Ohkubo; Tokutaro Komatsu; Nobuyuki Matsushita; Norimichi Kojima; Gunzi Saito

doi:10.1080/713738389

Crystal Structure and Physical Properties of BEDT-TTF (bis(ethylenedithio)tetrathiafulvalene) Salt Coupled with a Photo-Sensitive Transition Metal Complex

Masashi Ohkubo, Tokutaro Komatsu, Nobuyuki Matsushita, Norimichi Kojima, Gunzi Saito

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl 5 (NO)] 2− has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF + and NO exhibited a photo-induced effect.

Original language	English
Pages (from-to)	147-152
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals
Volume	376
Issue number	1
DOIs	https://doi.org/10.1080/713738389
Publication status	Published - 2002

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Crystal Structure and Physical Properties of BEDT-TTF (bis(ethylenedithio)tetrathiafulvalene) Salt Coupled with a Photo-Sensitive Transition Metal Complex",

abstract = "A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl 5 (NO)] 2− has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF + and NO exhibited a photo-induced effect.",

author = "Masashi Ohkubo and Tokutaro Komatsu and Nobuyuki Matsushita and Norimichi Kojima and Gunzi Saito",

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AU - Ohkubo, Masashi

AU - Komatsu, Tokutaro

AU - Matsushita, Nobuyuki

AU - Kojima, Norimichi

AU - Saito, Gunzi

PY - 2002

Y1 - 2002

N2 - A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl 5 (NO)] 2− has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF + and NO exhibited a photo-induced effect.

AB - A new salt of BEDT-TTF with photo-sensitive transition metal complex [RuCl 5 (NO)] 2− has been synthesized. The crystal structure was determined and attributed to the κ -type salt. Although calculated band structure shows two dimensional Fermi surfaces and predicts a metallic behavior, the resistivity shows semiconducting temperature dependence up to 6 kbar. Both the ESR signals of BEDT-TTF + and NO exhibited a photo-induced effect.

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Crystal Structure and Physical Properties of BEDT-TTF (bis(ethylenedithio)tetrathiafulvalene) Salt Coupled with a Photo-Sensitive Transition Metal Complex

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