Crystal structure and reactivity of a five-coordinate chloroiron(III) complex with a bulky tetradentate Schiff base ligand

Kenichi Oyaizu, Eishun Tsuchida

    Research output: Contribution to journalArticle

    22 Citations (Scopus)

    Abstract

    Crystal structure of [Fe(salphen)Cl] (H2salphen=N,N′-(1R, 2R)-1,2-diphenylethylenebis(salicylideneimine)) reveals that a steric effect induced by the bulky substituent on the Schiff base ligand brings about drastic changes in the reactivity of the complex; the typical dimerization of the chloroiron(III) complex upon basification to yield μ-oxo complexes are suppressed, resulting in the high-yielding conversion to a hydroxide salt.

    Original languageEnglish
    Pages (from-to)414-419
    Number of pages6
    JournalInorganica Chimica Acta
    Volume355
    DOIs
    Publication statusPublished - 2003 Nov 20

    Fingerprint

    Dimerization
    Schiff Bases
    dimerization
    imines
    hydroxides
    reactivity
    Salts
    Crystal structure
    Ligands
    salts
    ligands
    crystal structure
    salphen
    hydroxide ion

    Keywords

    • Chloroiron complexes
    • Crystal structures
    • Schiff base ligands

    ASJC Scopus subject areas

    • Biochemistry
    • Inorganic Chemistry
    • Physical and Theoretical Chemistry
    • Materials Chemistry

    Cite this

    Crystal structure and reactivity of a five-coordinate chloroiron(III) complex with a bulky tetradentate Schiff base ligand. / Oyaizu, Kenichi; Tsuchida, Eishun.

    In: Inorganica Chimica Acta, Vol. 355, 20.11.2003, p. 414-419.

    Research output: Contribution to journalArticle

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