Abstract
The title cyclometalated platinum(II) complex with 2-(4-bromophenyl)pyridinato and acetylacetonato ligands, [Pt(C11H7BrN)(C5H7O2)], consists of two crystallographically non-equivalent dimers, each stacked by π-π interactions with distances of ≃ 3.4Å. In both dimers, the platinum(II) complexes are arranged antiparallel to each other. Each complex exhibits a slightly distorted square-planar coordination environment around the central Pt(II) atom. The dihedral angles between two chelate rings including the PtII atom in these complexes are 0.08(12) and 1.54(9)°.
Original language | English |
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Pages (from-to) | 1259-1261 |
Number of pages | 3 |
Journal | Acta Crystallographica Section E: Crystallographic Communications |
Volume | 71 |
DOIs | |
Publication status | Published - 2015 |
Keywords
- acetylacetonato ligand
- crystal structure
- cyclometalated complex
- platinum(II)
- π-π interactions
ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics