Crystal structure of [5-bromo-2-(pyridin-2-yl-κN)phenyl-κC 1](pentane-2,4-dionato-κ 2 O,O′)platinum(II)

Keito Fukuda, Tomoaki Sugaya, Koji Ishihara

Research output: Contribution to journalArticlepeer-review

Abstract

The title cyclometalated platinum(II) complex with 2-(4-bromophenyl)pyridinato and acetylacetonato ligands, [Pt(C11H7BrN)(C5H7O2)], consists of two crystallographically non-equivalent dimers, each stacked by π-π interactions with distances of ≃ 3.4Å. In both dimers, the platinum(II) complexes are arranged antiparallel to each other. Each complex exhibits a slightly distorted square-planar coordination environment around the central Pt(II) atom. The dihedral angles between two chelate rings including the PtII atom in these complexes are 0.08(12) and 1.54(9)°.

Original languageEnglish
Pages (from-to)1259-1261
Number of pages3
JournalActa Crystallographica Section E: Crystallographic Communications
Volume71
DOIs
Publication statusPublished - 2015

Keywords

  • acetylacetonato ligand
  • crystal structure
  • cyclometalated complex
  • platinum(II)
  • π-π interactions

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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