Crystal structures of dimeric manganese(III) complexes of tetradentate Schiff-base ligands with ancillary axial donors

Kenichi Oyaizu, Takeshi Nakagawa, Eishun Tsuchida

    Research output: Contribution to journalArticle

    15 Citations (Scopus)

    Abstract

    [N,N'-Ethylenebis(salicylideneaminato)]manganese(III) benzoate ([Mn(salen)(O2CC6H5)] crystallized to form a solid-state dimer in which the Mn(salen) moiety is linked to its neighbor by two shared phenolate oxygen atoms, in striking contrast to the linear polymeric structure formed with bridging acetate ligands. A substantial cavity between the two manganese atoms was then produced by the weak coordination of the phenolate oxygen to the neighboring manganese bearing benzoate in a monodentate mode. (C) 2000 Elsevier Science S.A.

    Original languageEnglish
    Pages (from-to)184-188
    Number of pages5
    JournalInorganica Chimica Acta
    Volume305
    Issue number2
    DOIs
    Publication statusPublished - 2000 Jul 28

    Fingerprint

    Schiff Bases
    Manganese
    imines
    manganese
    Crystal structure
    Benzoates
    Ligands
    ligands
    crystal structure
    Bearings (structural)
    Oxygen
    Atoms
    Dimers
    acetates
    oxygen atoms
    Acetates
    dimers
    solid state
    cavities
    oxygen

    Keywords

    • Crystal structures
    • Dinuclear complexes
    • Manganese complexes
    • Schiff base complexes

    ASJC Scopus subject areas

    • Biochemistry
    • Inorganic Chemistry
    • Physical and Theoretical Chemistry
    • Materials Chemistry

    Cite this

    Crystal structures of dimeric manganese(III) complexes of tetradentate Schiff-base ligands with ancillary axial donors. / Oyaizu, Kenichi; Nakagawa, Takeshi; Tsuchida, Eishun.

    In: Inorganica Chimica Acta, Vol. 305, No. 2, 28.07.2000, p. 184-188.

    Research output: Contribution to journalArticle

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    KW - Dinuclear complexes

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    KW - Schiff base complexes

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