Crystal structures of dimeric manganese(III) complexes of tetradentate Schiff-base ligands with ancillary axial donors

Kenichi Oyaizu; Takeshi Nakagawa; Eishun Tsuchida

doi:10.1016/S0020-1693(00)00135-3

Crystal structures of dimeric manganese(III) complexes of tetradentate Schiff-base ligands with ancillary axial donors

Kenichi Oyaizu, Takeshi Nakagawa, Eishun Tsuchida^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

[N,N'-Ethylenebis(salicylideneaminato)]manganese(III) benzoate ([Mn(salen)(O₂CC₆H₅)] crystallized to form a solid-state dimer in which the Mn(salen) moiety is linked to its neighbor by two shared phenolate oxygen atoms, in striking contrast to the linear polymeric structure formed with bridging acetate ligands. A substantial cavity between the two manganese atoms was then produced by the weak coordination of the phenolate oxygen to the neighboring manganese bearing benzoate in a monodentate mode. (C) 2000 Elsevier Science S.A.

Original language	English
Pages (from-to)	184-188
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	305
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(00)00135-3
Publication status	Published - 2000 Jul 28

Keywords

Crystal structures
Dinuclear complexes
Manganese complexes
Schiff base complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(00)00135-3

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title = "Crystal structures of dimeric manganese(III) complexes of tetradentate Schiff-base ligands with ancillary axial donors",

abstract = "[N,N'-Ethylenebis(salicylideneaminato)]manganese(III) benzoate ([Mn(salen)(O2CC6H5)] crystallized to form a solid-state dimer in which the Mn(salen) moiety is linked to its neighbor by two shared phenolate oxygen atoms, in striking contrast to the linear polymeric structure formed with bridging acetate ligands. A substantial cavity between the two manganese atoms was then produced by the weak coordination of the phenolate oxygen to the neighboring manganese bearing benzoate in a monodentate mode. (C) 2000 Elsevier Science S.A.",

keywords = "Crystal structures, Dinuclear complexes, Manganese complexes, Schiff base complexes",

author = "Kenichi Oyaizu and Takeshi Nakagawa and Eishun Tsuchida",

note = "Funding Information: This work was partially supported by a Grant-in-Aid for Scientific Research Program (No. 11650878) from the Ministry of Education, Science, Sports and Culture, Japan.",

year = "2000",

month = jul,

day = "28",

doi = "10.1016/S0020-1693(00)00135-3",

language = "English",

volume = "305",

pages = "184--188",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

number = "2",

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TY - JOUR

T1 - Crystal structures of dimeric manganese(III) complexes of tetradentate Schiff-base ligands with ancillary axial donors

AU - Oyaizu, Kenichi

AU - Nakagawa, Takeshi

AU - Tsuchida, Eishun

N1 - Funding Information: This work was partially supported by a Grant-in-Aid for Scientific Research Program (No. 11650878) from the Ministry of Education, Science, Sports and Culture, Japan.

PY - 2000/7/28

Y1 - 2000/7/28

N2 - [N,N'-Ethylenebis(salicylideneaminato)]manganese(III) benzoate ([Mn(salen)(O2CC6H5)] crystallized to form a solid-state dimer in which the Mn(salen) moiety is linked to its neighbor by two shared phenolate oxygen atoms, in striking contrast to the linear polymeric structure formed with bridging acetate ligands. A substantial cavity between the two manganese atoms was then produced by the weak coordination of the phenolate oxygen to the neighboring manganese bearing benzoate in a monodentate mode. (C) 2000 Elsevier Science S.A.

AB - [N,N'-Ethylenebis(salicylideneaminato)]manganese(III) benzoate ([Mn(salen)(O2CC6H5)] crystallized to form a solid-state dimer in which the Mn(salen) moiety is linked to its neighbor by two shared phenolate oxygen atoms, in striking contrast to the linear polymeric structure formed with bridging acetate ligands. A substantial cavity between the two manganese atoms was then produced by the weak coordination of the phenolate oxygen to the neighboring manganese bearing benzoate in a monodentate mode. (C) 2000 Elsevier Science S.A.

KW - Crystal structures

KW - Dinuclear complexes

KW - Manganese complexes

KW - Schiff base complexes

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U2 - 10.1016/S0020-1693(00)00135-3

DO - 10.1016/S0020-1693(00)00135-3

M3 - Article

AN - SCOPUS:0034725545

SN - 0020-1693

VL - 305

SP - 184

EP - 188

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -

Crystal structures of dimeric manganese(III) complexes of tetradentate Schiff-base ligands with ancillary axial donors

Abstract

Keywords

ASJC Scopus subject areas

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