Crystallographic features and state stability of the decagonal quasicrystal in the Al-Co-Cu alloy system

Kei Nakayama, Akito Mizutani, Yasumasa Koyama

    Research output: Contribution to journalArticle

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    Abstract

    In the Al-Co-Cu alloy system, both the decagonal quasicrystal with the space group of P10m2 and its approximant Al13Co4 phase with monoclinic Cm symmetry are present around 20 at. % Co-10 at. % Cu. In this study, we examined the crystallographic features of prepared Al-(30 - x) at. % Co-x at. % Cu samples mainly by transmission electron microscopy in order to make clear the crystallographic relation between the decagonal quasicrystal and the monoclinic Al13Co4 structure. The results revealed a coexistence state consisting of decagonal quasicrystal and approximant Al13Co4regions in Al-20 at. % Co-10 at. % Cu alloy samples. With the help of the coexistence state, the orientation relationship was established between the monoclinic Al13Co4 structure and the decagonal quasicrystal. In the determined relationship, the crystallographic axis in the quasicrystal was found to be parallel to the normal direction of the (010)mplane in the Al13Co4 structure, where the subscript m denotes the monoclinic system. Based on data obtained experimentally, the state stability of the decagonal quasicrystal was also examined in terms of the Hume-Rothery (HR) mechanism on the basis of the nearly-free-electron approximation. It was found that a model based on the HR mechanism could explain the crystallographic features such as electron diffraction patterns and atomic arrangements found in the decagonal quasicrystal. In other words, the HR mechanism is most likely appropriate for the stability of the decagonal quasicrystal in the Al-Co-Cu alloy system.

    Original languageEnglish
    Article number114602
    JournalJournal of the Physical Society of Japan
    Volume85
    Issue number11
    DOIs
    Publication statusPublished - 2016 Nov 15

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    free electrons
    diffraction patterns
    electron diffraction
    transmission electron microscopy
    symmetry
    approximation

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    Cite this

    Crystallographic features and state stability of the decagonal quasicrystal in the Al-Co-Cu alloy system. / Nakayama, Kei; Mizutani, Akito; Koyama, Yasumasa.

    In: Journal of the Physical Society of Japan, Vol. 85, No. 11, 114602, 15.11.2016.

    Research output: Contribution to journalArticle

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    abstract = "In the Al-Co-Cu alloy system, both the decagonal quasicrystal with the space group of P10m2 and its approximant Al13Co4 phase with monoclinic Cm symmetry are present around 20 at. {\%} Co-10 at. {\%} Cu. In this study, we examined the crystallographic features of prepared Al-(30 - x) at. {\%} Co-x at. {\%} Cu samples mainly by transmission electron microscopy in order to make clear the crystallographic relation between the decagonal quasicrystal and the monoclinic Al13Co4 structure. The results revealed a coexistence state consisting of decagonal quasicrystal and approximant Al13Co4regions in Al-20 at. {\%} Co-10 at. {\%} Cu alloy samples. With the help of the coexistence state, the orientation relationship was established between the monoclinic Al13Co4 structure and the decagonal quasicrystal. In the determined relationship, the crystallographic axis in the quasicrystal was found to be parallel to the normal direction of the (010)mplane in the Al13Co4 structure, where the subscript m denotes the monoclinic system. Based on data obtained experimentally, the state stability of the decagonal quasicrystal was also examined in terms of the Hume-Rothery (HR) mechanism on the basis of the nearly-free-electron approximation. It was found that a model based on the HR mechanism could explain the crystallographic features such as electron diffraction patterns and atomic arrangements found in the decagonal quasicrystal. In other words, the HR mechanism is most likely appropriate for the stability of the decagonal quasicrystal in the Al-Co-Cu alloy system.",
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