Crystallographic features in the vicinity of the morphotropic phase boundary in the multiferroic material Bi1-xSmxFeO3

Masashi Nomoto, Takumi Inoshita, Yasuhide Inoue, Yoichi Horibe, Yasumasa Koyama

    Research output: Contribution to journalArticle

    2 Citations (Scopus)

    Abstract

    The multiferroic material Bi1-xSm xFeO3 shows ferroelectric and antiferromagnetic properties in the ground state of the Bi-rich side. When the Sm content increases from x = 0 in BiFeO3, the (ferroelectric-R3c → paraelectric-Pnma) state change occurs around x = 0.14. According to the previous studies on Bi1-xSm xFeO3, the state boundary between the R3c and Pnma states can be identified as a morphotropic phase boundary (MPB), which is nearly parallel to the temperature axis in the state diagram. The notable feature of Bi1-xSm xFeO3 is that a remarkable piezoelectric response was also found near the MPB. However, the origin of the remarkable response has not been understood sufficiently. In this study, thus, the crystallographic features in the vicinity of the MPB have been examined by x-ray powder diffraction and transmission electron microscopy. It was confirmed that the R3c and Pnma states were present for 0 ≤ x ≤ 0.15 and for 0.16 ≤ x ≤ 0.30, respectively. In addition to these states, there also existed the PbZrO3-type state around x = 0.15, which was identified as a modulated structure. Based on the analysis of the modulated structure, furthermore, it was suggested that the PbZrO3-type state could be regarded as a 2q state, which is characterized by two transverse modulation waves with k1 = [1/2 0 0]o and k2 = [0 1/2 0]o in the orthorhombic-Pnma notation.

    Original languageEnglish
    Pages (from-to)573-578
    Number of pages6
    JournalMRS Advances
    Volume1
    Issue number9
    DOIs
    Publication statusPublished - 2016 Jan 1

    Fingerprint

    Phase boundaries
    Ferroelectric materials
    Ground state
    Modulation
    Transmission electron microscopy
    X rays
    coding
    diagrams
    modulation
    transmission electron microscopy
    ground state
    diffraction
    Temperature
    x rays
    temperature

    Keywords

    • crystallographic structure
    • oxide
    • transmission electron microscopy (TEM)

    ASJC Scopus subject areas

    • Mechanical Engineering
    • Mechanics of Materials
    • Materials Science(all)
    • Condensed Matter Physics

    Cite this

    Crystallographic features in the vicinity of the morphotropic phase boundary in the multiferroic material Bi1-xSmxFeO3 . / Nomoto, Masashi; Inoshita, Takumi; Inoue, Yasuhide; Horibe, Yoichi; Koyama, Yasumasa.

    In: MRS Advances, Vol. 1, No. 9, 01.01.2016, p. 573-578.

    Research output: Contribution to journalArticle

    Nomoto, Masashi ; Inoshita, Takumi ; Inoue, Yasuhide ; Horibe, Yoichi ; Koyama, Yasumasa. / Crystallographic features in the vicinity of the morphotropic phase boundary in the multiferroic material Bi1-xSmxFeO3 In: MRS Advances. 2016 ; Vol. 1, No. 9. pp. 573-578.
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    AU - Horibe, Yoichi

    AU - Koyama, Yasumasa

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    AB - The multiferroic material Bi1-xSm xFeO3 shows ferroelectric and antiferromagnetic properties in the ground state of the Bi-rich side. When the Sm content increases from x = 0 in BiFeO3, the (ferroelectric-R3c → paraelectric-Pnma) state change occurs around x = 0.14. According to the previous studies on Bi1-xSm xFeO3, the state boundary between the R3c and Pnma states can be identified as a morphotropic phase boundary (MPB), which is nearly parallel to the temperature axis in the state diagram. The notable feature of Bi1-xSm xFeO3 is that a remarkable piezoelectric response was also found near the MPB. However, the origin of the remarkable response has not been understood sufficiently. In this study, thus, the crystallographic features in the vicinity of the MPB have been examined by x-ray powder diffraction and transmission electron microscopy. It was confirmed that the R3c and Pnma states were present for 0 ≤ x ≤ 0.15 and for 0.16 ≤ x ≤ 0.30, respectively. In addition to these states, there also existed the PbZrO3-type state around x = 0.15, which was identified as a modulated structure. Based on the analysis of the modulated structure, furthermore, it was suggested that the PbZrO3-type state could be regarded as a 2q state, which is characterized by two transverse modulation waves with k1 = [1/2 0 0]o and k2 = [0 1/2 0]o in the orthorhombic-Pnma notation.

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