Crystallographic features of La1-xSrxMO3 with M = Cr and Fe in the vicinity of the R3̄c/Pbnm phase boundary

M. Arao, H. Shindo, T. Asada, Yasumasa Koyama

    Research output: Contribution to journal › Article

    1 Citation (Scopus)

    Abstract

    Crystallographic features of La1-xSrxMO3 with M=Cr and Fe in the vicinity of the R3̄c/Pbnm phase boundary have been examined mainly at room temperature by transmission electron microscopy. When the Sr content x increases from x=0, the change in crystal structure from Pbnm to R3̄c was confirmed to occur at room temperature in La1-xSrxCrO3 around x=0.2. In La1-xSrxFeO3, on the other hand, the incommensurate phase was found to exist between the Pbnm and the R3̄c phases. The analysis of the electron diffraction patterns obtained in the work indicated that the normal structure of the incommensurate structure and the direction of the modulation could, respectively, be identified as the Pbnm structure and one of the 〈323〉 directions. It was also suggested that the rotational displacement of the oxygen octahedra involved in the Pbnm structure should be modulated in the incommensurate structure.

    Original languageEnglish
    Pages (from-to)137-141
    Number of pages5
    JournalPhysica C: Superconductivity and its Applications
    Volume378-381
    Issue numberPART 1
    DOIs
    Publication statusPublished - 2002 Oct 1

    Fingerprint

    Phase boundaries
    room temperature
    Electron diffraction
    Diffraction patterns
    diffraction patterns
    electron diffraction
    Crystal structure
    Modulation
    Oxygen
    Transmission electron microscopy
    modulation
    Temperature
    transmission electron microscopy
    crystal structure
    oxygen
    Direction compound

    Keywords

    • Incommensurate structure
    • LaSrFeO
    • LaSrCrO
    • R3̄c-to-Pbnm structural phase transition
    • Transmission electron microscopy

    ASJC Scopus subject areas

    • Condensed Matter Physics

    Cite this

    Crystallographic features of La1-xSrxMO3 with M = Cr and Fe in the vicinity of the R3̄c/Pbnm phase boundary. / Arao, M.; Shindo, H.; Asada, T.; Koyama, Yasumasa.

    In: Physica C: Superconductivity and its Applications, Vol. 378-381, No. PART 1, 01.10.2002, p. 137-141.

    Research output: Contribution to journal › Article

    Arao, M, Shindo, H, Asada, T & Koyama, Y 2002, 'Crystallographic features of La1-xSrxMO3 with M = Cr and Fe in the vicinity of the R3̄c/Pbnm phase boundary', Physica C: Superconductivity and its Applications, vol. 378-381, no. PART 1, pp. 137-141. https://doi.org/10.1016/S0921-4534(02)01398-9
    Arao M, Shindo H, Asada T, Koyama Y. Crystallographic features of La1-xSrxMO3 with M = Cr and Fe in the vicinity of the R3̄c/Pbnm phase boundary. Physica C: Superconductivity and its Applications. 2002 Oct 1;378-381(PART 1):137-141. https://doi.org/10.1016/S0921-4534(02)01398-9
    Arao, M. ; Shindo, H. ; Asada, T. ; Koyama, Yasumasa. / Crystallographic features of La1-xSrxMO3 with M = Cr and Fe in the vicinity of the R3̄c/Pbnm phase boundary. In: Physica C: Superconductivity and its Applications. 2002 ; Vol. 378-381, No. PART 1. pp. 137-141.
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    abstract = "Crystallographic features of La1-xSrxMO3 with M=Cr and Fe in the vicinity of the R3̄c/Pbnm phase boundary have been examined mainly at room temperature by transmission electron microscopy. When the Sr content x increases from x=0, the change in crystal structure from Pbnm to R3̄c was confirmed to occur at room temperature in La1-xSrxCrO3 around x=0.2. In La1-xSrxFeO3, on the other hand, the incommensurate phase was found to exist between the Pbnm and the R3̄c phases. The analysis of the electron diffraction patterns obtained in the work indicated that the normal structure of the incommensurate structure and the direction of the modulation could, respectively, be identified as the Pbnm structure and one of the 〈323〉 directions. It was also suggested that the rotational displacement of the oxygen octahedra involved in the Pbnm structure should be modulated in the incommensurate structure.",
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    AU - Asada, T.

    AU - Koyama, Yasumasa

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    N2 - Crystallographic features of La1-xSrxMO3 with M=Cr and Fe in the vicinity of the R3̄c/Pbnm phase boundary have been examined mainly at room temperature by transmission electron microscopy. When the Sr content x increases from x=0, the change in crystal structure from Pbnm to R3̄c was confirmed to occur at room temperature in La1-xSrxCrO3 around x=0.2. In La1-xSrxFeO3, on the other hand, the incommensurate phase was found to exist between the Pbnm and the R3̄c phases. The analysis of the electron diffraction patterns obtained in the work indicated that the normal structure of the incommensurate structure and the direction of the modulation could, respectively, be identified as the Pbnm structure and one of the 〈323〉 directions. It was also suggested that the rotational displacement of the oxygen octahedra involved in the Pbnm structure should be modulated in the incommensurate structure.

    AB - Crystallographic features of La1-xSrxMO3 with M=Cr and Fe in the vicinity of the R3̄c/Pbnm phase boundary have been examined mainly at room temperature by transmission electron microscopy. When the Sr content x increases from x=0, the change in crystal structure from Pbnm to R3̄c was confirmed to occur at room temperature in La1-xSrxCrO3 around x=0.2. In La1-xSrxFeO3, on the other hand, the incommensurate phase was found to exist between the Pbnm and the R3̄c phases. The analysis of the electron diffraction patterns obtained in the work indicated that the normal structure of the incommensurate structure and the direction of the modulation could, respectively, be identified as the Pbnm structure and one of the 〈323〉 directions. It was also suggested that the rotational displacement of the oxygen octahedra involved in the Pbnm structure should be modulated in the incommensurate structure.

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