Crystallographic features of RTiO3 (R

Rare-earth ion)

    Research output: Contribution to journalArticle

    2 Citations (Scopus)

    Abstract

    The crystallographic features of the simple perovskite oxides RTiO 3 with R = La, Nd, Sm and Y, which are known to be correlated-electron insulators, have been examined mainly at room temperature by transmission electron microscopy. Electron diffraction patterns indicated that the oxides with R=La and Nd have the space group Pbnm. In electron diffraction patterns of SmTiO3 and YTiO3, on the other hand, the twin splitting of reflections due to the Pbnm structure is seen along one of the 〈100〉c directions, where the subscript c denotes the cubic Brillouin zone. That is, it is understood that their crystal system is lowered from an orthorhombic one to a monoclinic one. The analysis of the patterns also suggested that the Jahn-Teller atomic displacement with q = 〈1/21/20〉c should be involved in the crystal structure for R = Sm and Y, in addition to the full symmetric Jahn-Teller lattice distortion in the structure for R = La and Nd.

    Original languageEnglish
    Pages (from-to)300-305
    Number of pages6
    JournalPhysica C: Superconductivity and its Applications
    Volume392-396
    Issue numberPART 1
    DOIs
    Publication statusPublished - 2003 Oct

    Fingerprint

    Electron diffraction
    Oxides
    Diffraction patterns
    Rare earths
    diffraction patterns
    rare earth elements
    electron diffraction
    Ions
    oxides
    Brillouin zones
    Perovskite
    ions
    Crystal structure
    insulators
    Transmission electron microscopy
    transmission electron microscopy
    Crystals
    crystal structure
    Electrons
    room temperature

    Keywords

    • Jahn-Teller atomic displacement
    • Jahn-Teller lattice distortion
    • RTiO (R: rare-earth ion)
    • Structural phase transition
    • Transmission electron microscopy

    ASJC Scopus subject areas

    • Condensed Matter Physics

    Cite this

    Crystallographic features of RTiO3 (R : Rare-earth ion). / Arao, M.; Koyama, Yasumasa.

    In: Physica C: Superconductivity and its Applications, Vol. 392-396, No. PART 1, 10.2003, p. 300-305.

    Research output: Contribution to journalArticle

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    abstract = "The crystallographic features of the simple perovskite oxides RTiO 3 with R = La, Nd, Sm and Y, which are known to be correlated-electron insulators, have been examined mainly at room temperature by transmission electron microscopy. Electron diffraction patterns indicated that the oxides with R=La and Nd have the space group Pbnm. In electron diffraction patterns of SmTiO3 and YTiO3, on the other hand, the twin splitting of reflections due to the Pbnm structure is seen along one of the 〈100〉c directions, where the subscript c denotes the cubic Brillouin zone. That is, it is understood that their crystal system is lowered from an orthorhombic one to a monoclinic one. The analysis of the patterns also suggested that the Jahn-Teller atomic displacement with q = 〈1/21/20〉c should be involved in the crystal structure for R = Sm and Y, in addition to the full symmetric Jahn-Teller lattice distortion in the structure for R = La and Nd.",
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    N2 - The crystallographic features of the simple perovskite oxides RTiO 3 with R = La, Nd, Sm and Y, which are known to be correlated-electron insulators, have been examined mainly at room temperature by transmission electron microscopy. Electron diffraction patterns indicated that the oxides with R=La and Nd have the space group Pbnm. In electron diffraction patterns of SmTiO3 and YTiO3, on the other hand, the twin splitting of reflections due to the Pbnm structure is seen along one of the 〈100〉c directions, where the subscript c denotes the cubic Brillouin zone. That is, it is understood that their crystal system is lowered from an orthorhombic one to a monoclinic one. The analysis of the patterns also suggested that the Jahn-Teller atomic displacement with q = 〈1/21/20〉c should be involved in the crystal structure for R = Sm and Y, in addition to the full symmetric Jahn-Teller lattice distortion in the structure for R = La and Nd.

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