Cyclic tetramer of a metalloporphyrin based on a quadruple hydrogen bond

Haruki Ohkawa, Akihiro Takayama, Satoshi Nakajima, Hiroyuki Nishide

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

This paper describes the selective formation of a cyclic tetramer from a readily synthesized metalloporphyrin with two self-complementary quadruple hydrogen-bonding units. The extremely strong quadruple hydrogen-bonding unit, 2-ureido-4[1H]-pyrimidinone, enabled the formation of a stable cyclic tetramer based on a tetraphenylporphyrin derivative over a wide concentration range. This hydrogen-bonded tetramer is a new functional unit for use in a higher-ordered architecture of a supramolecular porphyrin assembly.

Original languageEnglish
Pages (from-to)2225-2228
Number of pages4
JournalOrganic Letters
Volume8
Issue number11
DOIs
Publication statusPublished - 2006 May 25

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Metalloporphyrins
Hydrogen Bonding
Hydrogen
Hydrogen bonds
Pyrimidinones
hydrogen bonds
Porphyrins
hydrogen
Derivatives
porphyrins
assembly

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Cyclic tetramer of a metalloporphyrin based on a quadruple hydrogen bond. / Ohkawa, Haruki; Takayama, Akihiro; Nakajima, Satoshi; Nishide, Hiroyuki.

In: Organic Letters, Vol. 8, No. 11, 25.05.2006, p. 2225-2228.

Research output: Contribution to journalArticle

Ohkawa, Haruki ; Takayama, Akihiro ; Nakajima, Satoshi ; Nishide, Hiroyuki. / Cyclic tetramer of a metalloporphyrin based on a quadruple hydrogen bond. In: Organic Letters. 2006 ; Vol. 8, No. 11. pp. 2225-2228.
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