Decarbonylative C-P bond formation using aromatic esters and organophosphorus compounds

    Research output: Contribution to journalArticle

    28 Citations (Scopus)

    Abstract

    Ni-catalyzed C-P bond formation was achieved using aromatic esters as unconventional aryl sources. The key to success was the use of a thiophene-based diphosphine ligand (dcypt). Several aromatic esters including heteroaromatics can be coupled with phosphine oxides and phosphates, providing aryl phosphorus compounds. The synthetic utility of the method was demonstrated by application of the present protocol to the sequential coupling reactions.

    Original languageEnglish
    Pages (from-to)1150-1153
    Number of pages4
    JournalOrganic Letters
    Volume20
    Issue number4
    DOIs
    Publication statusPublished - 2018 Feb 16

    Fingerprint

    Organophosphorus Compounds
    phosphine
    esters
    Esters
    Phosphorus Compounds
    phosphorus compounds
    Thiophenes
    thiophenes
    phosphines
    Oxides
    phosphates
    Phosphates
    Ligands
    ligands
    oxides

    ASJC Scopus subject areas

    • Biochemistry
    • Physical and Theoretical Chemistry
    • Organic Chemistry

    Cite this

    Decarbonylative C-P bond formation using aromatic esters and organophosphorus compounds. / Isshiki, Ryota; Muto, Kei; Yamaguchi, Junichiro.

    In: Organic Letters, Vol. 20, No. 4, 16.02.2018, p. 1150-1153.

    Research output: Contribution to journalArticle

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