Dehydrogenation of methylcyclohexane over Pt/TiO2-Al2O3 catalysts

Yukihiro Sugiura, Tomomi Nagatsuka, Kouichi Kubo, Yuichiro Hirano, Akitoshi Nakamura, Kazunori Miyazawa, Yusuke Iizuka, Satoshi Furuta, Hideshi Iki, Takuma Higo, Yasushi Sekine

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9 Citations (Scopus)


Dehydrogenation of methylcyclohexane (MCH) was conducted over Pt/TiO2-Al2O3 catalysts, showing high activity, selectivity, stability, and high mechanical strength. XPS measurements revealed that the binding energy of Pt 4d5/2 shifted to a lower energy by adding TiO2 due to electron donation from TiO2. Formed toluene released immediately on electron-rich Pt before further decomposition to form methane and coke thanks to π-coordination. This phenomenon improved the catalytic performance, ensuring high selectivity, and durability for methylcyclohexane dehydrogenation.

Original languageEnglish
Pages (from-to)1601-1604
Number of pages4
JournalChemistry Letters
Issue number11
Publication statusPublished - 2017


  • Dehydrogenation of methylcyclohexane
  • Hydrogen carrier
  • Pt catalyst

ASJC Scopus subject areas

  • Chemistry(all)

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    Sugiura, Y., Nagatsuka, T., Kubo, K., Hirano, Y., Nakamura, A., Miyazawa, K., Iizuka, Y., Furuta, S., Iki, H., Higo, T., & Sekine, Y. (2017). Dehydrogenation of methylcyclohexane over Pt/TiO2-Al2O3 catalysts. Chemistry Letters, 46(11), 1601-1604.