Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules: Surface grafting studies

Rigoberto C. Advincula, Maria Celeste Tria

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Grafting of polymer brushes if of high interest towards intelligent materials systems with stimuli response. While there has been a lot of interest on chemically modified attachment of initiators towards surfaces for surface initiated polymerization (SIP), very little work has been done on modifying electrode surfaces via electrochemical methods. To address this issue, we have proposed to use a preformed RAFT agent with an electrochemically active moiety to mediate SI-RAFT polymerization as well as grafting of CTA's on electrode surfaces to promote RAFT-SIP. In particular, we have used the first generation CTA (G1-CTA), which had been reported to facilitate RAFT polymerization in solution. The presence of the electro-active carbazole group in this RAFT agent enables its immobilization on the electrode surface through electro-grafting.

Original languageEnglish
Title of host publicationSmart Coatings III
PublisherAmerican Chemical Society
Pages63-72
Number of pages10
Volume1050
ISBN (Print)9780841225657
DOIs
Publication statusPublished - 2010 Nov 10
Externally publishedYes

Publication series

NameACS Symposium Series
Volume1050
ISSN (Print)0097-6156
ISSN (Electronic)1947-5918

Fingerprint

Macromolecules
Polymerization
Electrodes
Intelligent materials
Brushes
dendron
Polymers

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Advincula, R. C., & Tria, M. C. (2010). Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules: Surface grafting studies. In Smart Coatings III (Vol. 1050, pp. 63-72). (ACS Symposium Series; Vol. 1050). American Chemical Society. https://doi.org/10.1021/bk-2010-1050.ch005

Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules : Surface grafting studies. / Advincula, Rigoberto C.; Tria, Maria Celeste.

Smart Coatings III. Vol. 1050 American Chemical Society, 2010. p. 63-72 (ACS Symposium Series; Vol. 1050).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Advincula, RC & Tria, MC 2010, Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules: Surface grafting studies. in Smart Coatings III. vol. 1050, ACS Symposium Series, vol. 1050, American Chemical Society, pp. 63-72. https://doi.org/10.1021/bk-2010-1050.ch005
Advincula RC, Tria MC. Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules: Surface grafting studies. In Smart Coatings III. Vol. 1050. American Chemical Society. 2010. p. 63-72. (ACS Symposium Series). https://doi.org/10.1021/bk-2010-1050.ch005
Advincula, Rigoberto C. ; Tria, Maria Celeste. / Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules : Surface grafting studies. Smart Coatings III. Vol. 1050 American Chemical Society, 2010. pp. 63-72 (ACS Symposium Series).
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