Development of Hierarchical Pore Systems for Zeolite Catalysts

Masaru Ogura, Masahiko Matsukata

    Research output: Chapter in Book/Report/Conference proceedingChapter

    2 Citations (Scopus)

    Abstract

    This chapter reviews desilication and the effect of desilication on the zeolite framework. It also reviews the mechanism of desilication, and its potential applications. Silicalite-1 is the all-silica version of ZSM-5. The desilication behavior of all silica zeolite would provide great insight to understand the progress of desilication and dissolution of the siliceous part of zeolite. Desilicated zeolite can function as a host not only for small components such as Fe(III) metal cations but also for larger macromolecules such as enzymes. The chapter describes the changes occurring throughout the alkali (alkaline) treatment of zeolites. ZSM-5 and other medium-pore, small-pore, and low-dimensional microporous zeolites are impacted by this treatment, resulting in significant improvement of diffusivity throughout their intrinsic microporous structure.

    Original languageEnglish
    Title of host publicationMesoporous Zeolites
    Subtitle of host publicationPreparation, Characterization and Applications
    PublisherWiley-VCH Verlag
    Pages259-294
    Number of pages36
    ISBN (Electronic)9783527673957
    ISBN (Print)9783527335749
    DOIs
    Publication statusPublished - 2015 Jul 24

    Fingerprint

    Zeolites
    Silica
    Catalysts
    Macromolecules
    Dissolution
    Enzymes
    Positive ions
    Silicon Dioxide
    Metals
    Alkalies
    Cations

    Keywords

    • Alkali treatment
    • Desilicated zeolite
    • Microporous zeolites
    • ZSM-5

    ASJC Scopus subject areas

    • Engineering(all)
    • Materials Science(all)

    Cite this

    Ogura, M., & Matsukata, M. (2015). Development of Hierarchical Pore Systems for Zeolite Catalysts. In Mesoporous Zeolites: Preparation, Characterization and Applications (pp. 259-294). Wiley-VCH Verlag. https://doi.org/10.1002/9783527673957.ch8

    Development of Hierarchical Pore Systems for Zeolite Catalysts. / Ogura, Masaru; Matsukata, Masahiko.

    Mesoporous Zeolites: Preparation, Characterization and Applications. Wiley-VCH Verlag, 2015. p. 259-294.

    Research output: Chapter in Book/Report/Conference proceedingChapter

    Ogura, M & Matsukata, M 2015, Development of Hierarchical Pore Systems for Zeolite Catalysts. in Mesoporous Zeolites: Preparation, Characterization and Applications. Wiley-VCH Verlag, pp. 259-294. https://doi.org/10.1002/9783527673957.ch8
    Ogura M, Matsukata M. Development of Hierarchical Pore Systems for Zeolite Catalysts. In Mesoporous Zeolites: Preparation, Characterization and Applications. Wiley-VCH Verlag. 2015. p. 259-294 https://doi.org/10.1002/9783527673957.ch8
    Ogura, Masaru ; Matsukata, Masahiko. / Development of Hierarchical Pore Systems for Zeolite Catalysts. Mesoporous Zeolites: Preparation, Characterization and Applications. Wiley-VCH Verlag, 2015. pp. 259-294
    @inbook{d5f788d21ad54631b7bcd185f107d655,
    title = "Development of Hierarchical Pore Systems for Zeolite Catalysts",
    abstract = "This chapter reviews desilication and the effect of desilication on the zeolite framework. It also reviews the mechanism of desilication, and its potential applications. Silicalite-1 is the all-silica version of ZSM-5. The desilication behavior of all silica zeolite would provide great insight to understand the progress of desilication and dissolution of the siliceous part of zeolite. Desilicated zeolite can function as a host not only for small components such as Fe(III) metal cations but also for larger macromolecules such as enzymes. The chapter describes the changes occurring throughout the alkali (alkaline) treatment of zeolites. ZSM-5 and other medium-pore, small-pore, and low-dimensional microporous zeolites are impacted by this treatment, resulting in significant improvement of diffusivity throughout their intrinsic microporous structure.",
    keywords = "Alkali treatment, Desilicated zeolite, Microporous zeolites, ZSM-5",
    author = "Masaru Ogura and Masahiko Matsukata",
    year = "2015",
    month = "7",
    day = "24",
    doi = "10.1002/9783527673957.ch8",
    language = "English",
    isbn = "9783527335749",
    pages = "259--294",
    booktitle = "Mesoporous Zeolites",
    publisher = "Wiley-VCH Verlag",

    }

    TY - CHAP

    T1 - Development of Hierarchical Pore Systems for Zeolite Catalysts

    AU - Ogura, Masaru

    AU - Matsukata, Masahiko

    PY - 2015/7/24

    Y1 - 2015/7/24

    N2 - This chapter reviews desilication and the effect of desilication on the zeolite framework. It also reviews the mechanism of desilication, and its potential applications. Silicalite-1 is the all-silica version of ZSM-5. The desilication behavior of all silica zeolite would provide great insight to understand the progress of desilication and dissolution of the siliceous part of zeolite. Desilicated zeolite can function as a host not only for small components such as Fe(III) metal cations but also for larger macromolecules such as enzymes. The chapter describes the changes occurring throughout the alkali (alkaline) treatment of zeolites. ZSM-5 and other medium-pore, small-pore, and low-dimensional microporous zeolites are impacted by this treatment, resulting in significant improvement of diffusivity throughout their intrinsic microporous structure.

    AB - This chapter reviews desilication and the effect of desilication on the zeolite framework. It also reviews the mechanism of desilication, and its potential applications. Silicalite-1 is the all-silica version of ZSM-5. The desilication behavior of all silica zeolite would provide great insight to understand the progress of desilication and dissolution of the siliceous part of zeolite. Desilicated zeolite can function as a host not only for small components such as Fe(III) metal cations but also for larger macromolecules such as enzymes. The chapter describes the changes occurring throughout the alkali (alkaline) treatment of zeolites. ZSM-5 and other medium-pore, small-pore, and low-dimensional microporous zeolites are impacted by this treatment, resulting in significant improvement of diffusivity throughout their intrinsic microporous structure.

    KW - Alkali treatment

    KW - Desilicated zeolite

    KW - Microporous zeolites

    KW - ZSM-5

    UR - http://www.scopus.com/inward/record.url?scp=84938850227&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=84938850227&partnerID=8YFLogxK

    U2 - 10.1002/9783527673957.ch8

    DO - 10.1002/9783527673957.ch8

    M3 - Chapter

    SN - 9783527335749

    SP - 259

    EP - 294

    BT - Mesoporous Zeolites

    PB - Wiley-VCH Verlag

    ER -