Diamond-shaped [Ag 4] 4+ cluster encapsulated by silicotungstate ligands

Synthesis and catalysis of hydrolytic oxidation of silanes

Yuji Kikukawa, Yoshiyuki Kuroda, Kazuya Yamaguchi, Noritaka Mizuno

Research output: Contribution to journal › Article

71 Citations (Scopus)

Abstract

An Ag 4 diamond is encapsulated by silicotungstate ligands in TBA 8[Ag 4(DMSO) 2(γ-H 2SiW 10O 36) 2]·2 DMSO·2 H 2O (Ag4; DMSO=dimethyl sulfoxide, TBA=tetra-n-butylammonium), which was obtained by reaction of TBA 4H 4[γ-SiW 10O 36] with AgOAc in an organic medium. Polyoxometalate Ag4 (see picture) selectively catalyzes hydrolytic oxidation of various silanes to the corresponding silanols in high yields (72-96 %).

Original languageEnglish
Pages (from-to)2434-2437
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number10
DOIs
Publication statusPublished - 2012 Mar 5
Externally publishedYes

Fingerprint

Silanes
Diamond
Dimethyl sulfoxide
Dimethyl Sulfoxide
Catalysis
Diamonds
Ligands
Oxidation

Keywords

  • cluster compounds
  • oxidation
  • polyoxometalates
  • silver
  • synthetic methods

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Diamond-shaped [Ag 4] 4+ cluster encapsulated by silicotungstate ligands : Synthesis and catalysis of hydrolytic oxidation of silanes. / Kikukawa, Yuji; Kuroda, Yoshiyuki; Yamaguchi, Kazuya; Mizuno, Noritaka.

In: Angewandte Chemie - International Edition, Vol. 51, No. 10, 05.03.2012, p. 2434-2437.

Research output: Contribution to journal › Article

Kikukawa, Y, Kuroda, Y, Yamaguchi, K & Mizuno, N 2012, 'Diamond-shaped [Ag 4] 4+ cluster encapsulated by silicotungstate ligands: Synthesis and catalysis of hydrolytic oxidation of silanes', Angewandte Chemie - International Edition, vol. 51, no. 10, pp. 2434-2437. https://doi.org/10.1002/anie.201108372
Kikukawa Y, Kuroda Y, Yamaguchi K, Mizuno N. Diamond-shaped [Ag 4] 4+ cluster encapsulated by silicotungstate ligands: Synthesis and catalysis of hydrolytic oxidation of silanes. Angewandte Chemie - International Edition. 2012 Mar 5;51(10):2434-2437. https://doi.org/10.1002/anie.201108372
Kikukawa, Yuji ; Kuroda, Yoshiyuki ; Yamaguchi, Kazuya ; Mizuno, Noritaka. / Diamond-shaped [Ag 4] 4+ cluster encapsulated by silicotungstate ligands : Synthesis and catalysis of hydrolytic oxidation of silanes. In: Angewandte Chemie - International Edition. 2012 ; Vol. 51, No. 10. pp. 2434-2437.
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