Abstract
The intrinsic breakdown strength of tetraethoxysilane-SiO2 film is estimated via the self-healing technique with 1 us-width pulse voltages. The intrinsic breakdown strength is shown to decrease when the deposition temperature exceeds 400°C. The appearance of oxygen vacancies in the samples deposited at high temperatures is confirmed through the measurements of optical absorption at 7.6 eV and luminescence at 4.4 eV with synchroton radiation photons. The breakdown strength increases upon oxygen treatment which reduces the amount of oxygen vacancies. From these results, it is considered that the oxygen vacancies play an important role in lowering the breakdown strength. Three possible mechanisms are discussed.
Original language | English |
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Title of host publication | IEEE International Conference on Conduction & Breakdown in Solid Dielectrics |
Place of Publication | Piscataway, NJ, United States |
Publisher | IEEE |
Pages | 656-660 |
Number of pages | 5 |
Publication status | Published - 1995 |
Event | Proceedings of the 1995 IEEE 5th International Conference on Conduction and Breakdown in Solid Dielectrics - Leicester, Engl Duration: 1995 Jul 10 → 1995 Jul 13 |
Other
Other | Proceedings of the 1995 IEEE 5th International Conference on Conduction and Breakdown in Solid Dielectrics |
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City | Leicester, Engl |
Period | 95/7/10 → 95/7/13 |
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ASJC Scopus subject areas
- Engineering(all)
Cite this
Dielectric breakdown of SiO2 formed by plasma-enhanced chemical vapor deposition of tetraethoxysilane. / Ishii, Keisuke; Isshiki, Daisuke; Karasawa, Toshifumi; Ohki, Yoshimichi.
IEEE International Conference on Conduction & Breakdown in Solid Dielectrics. Piscataway, NJ, United States : IEEE, 1995. p. 656-660.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
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TY - GEN
T1 - Dielectric breakdown of SiO2 formed by plasma-enhanced chemical vapor deposition of tetraethoxysilane
AU - Ishii, Keisuke
AU - Isshiki, Daisuke
AU - Karasawa, Toshifumi
AU - Ohki, Yoshimichi
PY - 1995
Y1 - 1995
N2 - The intrinsic breakdown strength of tetraethoxysilane-SiO2 film is estimated via the self-healing technique with 1 us-width pulse voltages. The intrinsic breakdown strength is shown to decrease when the deposition temperature exceeds 400°C. The appearance of oxygen vacancies in the samples deposited at high temperatures is confirmed through the measurements of optical absorption at 7.6 eV and luminescence at 4.4 eV with synchroton radiation photons. The breakdown strength increases upon oxygen treatment which reduces the amount of oxygen vacancies. From these results, it is considered that the oxygen vacancies play an important role in lowering the breakdown strength. Three possible mechanisms are discussed.
AB - The intrinsic breakdown strength of tetraethoxysilane-SiO2 film is estimated via the self-healing technique with 1 us-width pulse voltages. The intrinsic breakdown strength is shown to decrease when the deposition temperature exceeds 400°C. The appearance of oxygen vacancies in the samples deposited at high temperatures is confirmed through the measurements of optical absorption at 7.6 eV and luminescence at 4.4 eV with synchroton radiation photons. The breakdown strength increases upon oxygen treatment which reduces the amount of oxygen vacancies. From these results, it is considered that the oxygen vacancies play an important role in lowering the breakdown strength. Three possible mechanisms are discussed.
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M3 - Conference contribution
AN - SCOPUS:0029540456
SP - 656
EP - 660
BT - IEEE International Conference on Conduction & Breakdown in Solid Dielectrics
PB - IEEE
CY - Piscataway, NJ, United States
ER -