DIELECTRIC PROPERTIES AND ESCA SPECTRUM OF PLASMA POLYMERIZED ETHYLENE FILMS.

N. Hozumi, T. Takao, Y. Kasama, Yoshimichi Ohki, M. Masui

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    The effect of atmosphere after polymerization on dielectric properties of plasma polymerized ethylene (ppe) is studied. Electron Spectroscopy for Chemical Analysis (ESCA) and Electron Spin Resonance (ESR) measurements show that the PPE sample traps oxygen rapidly when it is exposed to air after polymerization. They also show that heat treatment in argon or in hydrogen can reduce the number of residual free radicals. The change in dielectric properties like dissipation factor (tan delta ) and conduction current with atmosphere after polymerization can be explained if dielectric properties are closely related to residual free radicals and carbonyl groups formed in the sample.

    Original languageEnglish
    Title of host publicationProceedings of the Symposium on Electrical Insulating Materials
    Place of PublicationTokyo, Jpn
    PublisherInst of Electrical Engineers of Japan
    Pages167-170
    Number of pages4
    Publication statusPublished - 1982

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    Electron spectroscopy
    Dielectric properties
    Ethylene
    Polymerization
    Free radicals
    Plasmas
    Chemical analysis
    Paramagnetic resonance
    Argon
    Heat treatment
    Hydrogen
    Oxygen
    Air

    ASJC Scopus subject areas

    • Engineering(all)

    Cite this

    Hozumi, N., Takao, T., Kasama, Y., Ohki, Y., & Masui, M. (1982). DIELECTRIC PROPERTIES AND ESCA SPECTRUM OF PLASMA POLYMERIZED ETHYLENE FILMS. In Proceedings of the Symposium on Electrical Insulating Materials (pp. 167-170). Tokyo, Jpn: Inst of Electrical Engineers of Japan.

    DIELECTRIC PROPERTIES AND ESCA SPECTRUM OF PLASMA POLYMERIZED ETHYLENE FILMS. / Hozumi, N.; Takao, T.; Kasama, Y.; Ohki, Yoshimichi; Masui, M.

    Proceedings of the Symposium on Electrical Insulating Materials. Tokyo, Jpn : Inst of Electrical Engineers of Japan, 1982. p. 167-170.

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Hozumi, N, Takao, T, Kasama, Y, Ohki, Y & Masui, M 1982, DIELECTRIC PROPERTIES AND ESCA SPECTRUM OF PLASMA POLYMERIZED ETHYLENE FILMS. in Proceedings of the Symposium on Electrical Insulating Materials. Inst of Electrical Engineers of Japan, Tokyo, Jpn, pp. 167-170.
    Hozumi N, Takao T, Kasama Y, Ohki Y, Masui M. DIELECTRIC PROPERTIES AND ESCA SPECTRUM OF PLASMA POLYMERIZED ETHYLENE FILMS. In Proceedings of the Symposium on Electrical Insulating Materials. Tokyo, Jpn: Inst of Electrical Engineers of Japan. 1982. p. 167-170
    Hozumi, N. ; Takao, T. ; Kasama, Y. ; Ohki, Yoshimichi ; Masui, M. / DIELECTRIC PROPERTIES AND ESCA SPECTRUM OF PLASMA POLYMERIZED ETHYLENE FILMS. Proceedings of the Symposium on Electrical Insulating Materials. Tokyo, Jpn : Inst of Electrical Engineers of Japan, 1982. pp. 167-170
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    abstract = "The effect of atmosphere after polymerization on dielectric properties of plasma polymerized ethylene (ppe) is studied. Electron Spectroscopy for Chemical Analysis (ESCA) and Electron Spin Resonance (ESR) measurements show that the PPE sample traps oxygen rapidly when it is exposed to air after polymerization. They also show that heat treatment in argon or in hydrogen can reduce the number of residual free radicals. The change in dielectric properties like dissipation factor (tan delta ) and conduction current with atmosphere after polymerization can be explained if dielectric properties are closely related to residual free radicals and carbonyl groups formed in the sample.",
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