Dielectric Properties of Water and Water/Ethylene Glycol Mixtures for Use in Pulsed Power System Design

Markus Zahn, Yoshimichi Ohki, David B. Fenneman, Ronald J. Gripshover, Victor H. Gehman

    Research output: Contribution to journalArticle

    106 Citations (Scopus)

    Abstract

    One class of modern pulse power generators use deionized water as an energy storage, switching and transmission dielectric. Water is chosen for its high dielectric constant and relatively high resistivity, which allows reasonably sized and efficient low-impedance high-voltage pulse lines where pulse durations are less than 100 ps. Water/ethylene glycol mixtures are being researched, so that rotating machinery, rather than the usual Marx generator, can be used as the primary energy store. The high resistivity and high dielectric constant of these mixtures at low temperature permit low-loss operation on millisecond time scales. Simple design criteria linking load parameters and charging circuit characteristics to the liquid dielectric are developed which show that the dielectric constant, breakdown strength, and relaxation time are the primary properties of interest to the pulse power engineer. On time scales greater than 100 p.s, injection of space charge, with density q and mobility µ, affects the charging and discharging circuit characteristics, introduces the time constant of the time of flight for injected charge to migrate between electrodes, and increases the effective ohmic conductivity σ to σ + qμ.A drift-dominated conduction model is used to describe measured space-charge effects. Kerr electrooptic field mapping measurements show strong space-charge effects with significant distortions in the electric field distribution a few hundred microseconds after high voltage is applied. The injected charge magnitude and sign depends on the electrode material. Thus by appropriate choice of electrode material combinations and voltage polarity, it is possible to have uncharged liquid, unipolar-charged negative or positive, or bipolar-charged liquid. An important case is that of bipolar injection, which has allowed up to a 40 percent higher applied voltage without breakdown than with no charge injection, and thus a doubling of stored energy due to the space-charge shielding which lowers the electric field strengths at both electrodes. Although injected space charge increases the stored electric energy over the capacitive space-charge-free energy, (1/2)CV2, more energy is required from a source during charging and the energy delivered to a resistive load is reduced because of internal dissipation in the capacitor as the charge is conducted to the electrodes. However, it appears that this extra dissipation due to injected charge can be made negligibly small and well worth the price if the space charge allows higher voltage operation for long charging time or repetitively operated machines.

    Original languageEnglish
    Pages (from-to)1182-1221
    Number of pages40
    JournalProceedings of the IEEE
    Volume74
    Issue number9
    DOIs
    Publication statusPublished - 1986

    Fingerprint

    Ethylene glycol
    Electric space charge
    Dielectric properties
    Systems analysis
    Electrodes
    Water
    Permittivity
    Electric potential
    Electric fields
    Dielectric liquids
    Charge injection
    Rotating machinery
    Networks (circuits)
    Deionized water
    Liquids
    Electrooptical effects
    Electric breakdown
    Shielding
    Relaxation time
    Energy storage

    ASJC Scopus subject areas

    • Electrical and Electronic Engineering

    Cite this

    Dielectric Properties of Water and Water/Ethylene Glycol Mixtures for Use in Pulsed Power System Design. / Zahn, Markus; Ohki, Yoshimichi; Fenneman, David B.; Gripshover, Ronald J.; Gehman, Victor H.

    In: Proceedings of the IEEE, Vol. 74, No. 9, 1986, p. 1182-1221.

    Research output: Contribution to journalArticle

    Zahn, Markus ; Ohki, Yoshimichi ; Fenneman, David B. ; Gripshover, Ronald J. ; Gehman, Victor H. / Dielectric Properties of Water and Water/Ethylene Glycol Mixtures for Use in Pulsed Power System Design. In: Proceedings of the IEEE. 1986 ; Vol. 74, No. 9. pp. 1182-1221.
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    abstract = "One class of modern pulse power generators use deionized water as an energy storage, switching and transmission dielectric. Water is chosen for its high dielectric constant and relatively high resistivity, which allows reasonably sized and efficient low-impedance high-voltage pulse lines where pulse durations are less than 100 ps. Water/ethylene glycol mixtures are being researched, so that rotating machinery, rather than the usual Marx generator, can be used as the primary energy store. The high resistivity and high dielectric constant of these mixtures at low temperature permit low-loss operation on millisecond time scales. Simple design criteria linking load parameters and charging circuit characteristics to the liquid dielectric are developed which show that the dielectric constant, breakdown strength, and relaxation time are the primary properties of interest to the pulse power engineer. On time scales greater than 100 p.s, injection of space charge, with density q and mobility µ, affects the charging and discharging circuit characteristics, introduces the time constant of the time of flight for injected charge to migrate between electrodes, and increases the effective ohmic conductivity σ to σ + qμ.A drift-dominated conduction model is used to describe measured space-charge effects. Kerr electrooptic field mapping measurements show strong space-charge effects with significant distortions in the electric field distribution a few hundred microseconds after high voltage is applied. The injected charge magnitude and sign depends on the electrode material. Thus by appropriate choice of electrode material combinations and voltage polarity, it is possible to have uncharged liquid, unipolar-charged negative or positive, or bipolar-charged liquid. An important case is that of bipolar injection, which has allowed up to a 40 percent higher applied voltage without breakdown than with no charge injection, and thus a doubling of stored energy due to the space-charge shielding which lowers the electric field strengths at both electrodes. Although injected space charge increases the stored electric energy over the capacitive space-charge-free energy, (1/2)CV2, more energy is required from a source during charging and the energy delivered to a resistive load is reduced because of internal dissipation in the capacitor as the charge is conducted to the electrodes. However, it appears that this extra dissipation due to injected charge can be made negligibly small and well worth the price if the space charge allows higher voltage operation for long charging time or repetitively operated machines.",
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