Diffusion-Cooperative Model for Charge Transport by Redox-Active Nonconjugated Polymers

Kan Hatakeyama, Rieka Ichinoi, Ryusuke Mizukami, Takuma Serikawa, Yusuke Sasaki, Jodie Lutkenhaus, Hiroyuki Nishide, Kenichi Oyaizu

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Charge transport processes in nonconjugated redox-active polymers with electrolytes were studied using a diffusion-cooperative model. For the first time, we quantitatively rationalized that the limited Brownian motion of the redox centers bound to the polymers resulted in the 103-4-fold decline of the bimolecular and heterogeneous charge transfer rate constants, which had been unexplained for half a century. As a next-generation design, a redox-active supramolecular system with high physical mobility was proposed to achieve the rate constant as high as in free solution system (>107 M-1 s-1) and populated site density (>1 mol/L).

Original languageEnglish
Pages (from-to)1049-1056
Number of pages8
JournalJournal of the American Chemical Society
Volume140
Issue number3
DOIs
Publication statusPublished - 2018 Jan 24

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Active Biological Transport
Oxidation-Reduction
Charge transfer
Polymers
Rate constants
Brownian movement
Electrolytes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Diffusion-Cooperative Model for Charge Transport by Redox-Active Nonconjugated Polymers. / Hatakeyama, Kan; Ichinoi, Rieka; Mizukami, Ryusuke; Serikawa, Takuma; Sasaki, Yusuke; Lutkenhaus, Jodie; Nishide, Hiroyuki; Oyaizu, Kenichi.

In: Journal of the American Chemical Society, Vol. 140, No. 3, 24.01.2018, p. 1049-1056.

Research output: Contribution to journalArticle

Hatakeyama, Kan ; Ichinoi, Rieka ; Mizukami, Ryusuke ; Serikawa, Takuma ; Sasaki, Yusuke ; Lutkenhaus, Jodie ; Nishide, Hiroyuki ; Oyaizu, Kenichi. / Diffusion-Cooperative Model for Charge Transport by Redox-Active Nonconjugated Polymers. In: Journal of the American Chemical Society. 2018 ; Vol. 140, No. 3. pp. 1049-1056.
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