Dinuclear manganese(II) complex containing tetrakis(2-pyridyl)methane as a spiro-fused bridge

Atsushi Okazawa, Takayuki Ishida*, Takashi Nogami

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

A dinuclear manganese(II) complex [{Mn(hfac)2} 2(py4C)] was synthesized, where hfac and py4C denote 1,1,1,5,5,5-hexafluoropentane-2,4-dionate and tetrakis(2-pyridyl)methane, respectively. X-Ray crystallographic analysis revealed that the dihedral angle was 87.4(2)° between two chelate rings around the spiro center. Very weak antiferromagnetic interaction is operative between manganese(II) spins.

Original languageEnglish
Pages (from-to)1478-1479
Number of pages2
JournalChemistry Letters
Volume33
Issue number11
DOIs
Publication statusPublished - 2004 Nov 5
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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