Dipped adcluster model and SAC-CI method applied to harpooning, chemiluminescence and electron emission in halogen chemisorption on alkali metal surface

H. Nakatsuji, R. Kuwano, H. Morita, H. Nakai

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

The methodology of our laboratory, the dipped adcluster model (DAM) and the symmetry adapted cluster configuration interaction (SAC-CI) method, are briefly reviewed and successfully applied to the electron transfer processes, harpooning, surface chemiluminescence, and surface electron emission, in the course of the chemisorption of halogen molecule on an alkali metal surface. This success encourages us to apply our methodology to surface photochemistry.

Original languageEnglish
Pages (from-to)211-228
Number of pages18
JournalJournal of Molecular Catalysis
Volume82
Issue number2-3
DOIs
Publication statusPublished - 1993 Jun 29
Externally publishedYes

Keywords

  • alkali-metal surface
  • chemiluminescence
  • electron emission
  • halogen chemisorption
  • harpooning

ASJC Scopus subject areas

  • Engineering(all)

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