Direct hydrogenation of carboxylic acids to corresponding aldehydes catalyzed by palladium complexes in the presence of pivalic anhydride

Kazuhiro Nagayama, Isao Shimizu, Akio Yamamoto

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

Carboxylic acids are catalytically hydrogenated into corresponding aldehydes by palladium complexes in the presence of pivalic (trimethylacetic) anhydride under H2. Less hindered aliphatic and aromatic acids are reduced to aldehydes in high yields The method is also applicable to hydrogenation of dibasic carboxylic acids and carboxylic acids containing heterocyclic groups.

Original languageEnglish
Pages (from-to)1143-1144
Number of pages2
JournalChemistry Letters
Issue number11
Publication statusPublished - 1998

Fingerprint

Palladium
Carboxylic Acids
Aldehydes
Hydrogenation
Carboxylic acids
pivalic anhydride

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Direct hydrogenation of carboxylic acids to corresponding aldehydes catalyzed by palladium complexes in the presence of pivalic anhydride. / Nagayama, Kazuhiro; Shimizu, Isao; Yamamoto, Akio.

In: Chemistry Letters, No. 11, 1998, p. 1143-1144.

Research output: Contribution to journalArticle

@article{eb972e5cfaf24e308d6fe03444e6ec86,
title = "Direct hydrogenation of carboxylic acids to corresponding aldehydes catalyzed by palladium complexes in the presence of pivalic anhydride",
abstract = "Carboxylic acids are catalytically hydrogenated into corresponding aldehydes by palladium complexes in the presence of pivalic (trimethylacetic) anhydride under H2. Less hindered aliphatic and aromatic acids are reduced to aldehydes in high yields The method is also applicable to hydrogenation of dibasic carboxylic acids and carboxylic acids containing heterocyclic groups.",
author = "Kazuhiro Nagayama and Isao Shimizu and Akio Yamamoto",
year = "1998",
language = "English",
pages = "1143--1144",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "Chemical Society of Japan",
number = "11",

}

TY - JOUR

T1 - Direct hydrogenation of carboxylic acids to corresponding aldehydes catalyzed by palladium complexes in the presence of pivalic anhydride

AU - Nagayama, Kazuhiro

AU - Shimizu, Isao

AU - Yamamoto, Akio

PY - 1998

Y1 - 1998

N2 - Carboxylic acids are catalytically hydrogenated into corresponding aldehydes by palladium complexes in the presence of pivalic (trimethylacetic) anhydride under H2. Less hindered aliphatic and aromatic acids are reduced to aldehydes in high yields The method is also applicable to hydrogenation of dibasic carboxylic acids and carboxylic acids containing heterocyclic groups.

AB - Carboxylic acids are catalytically hydrogenated into corresponding aldehydes by palladium complexes in the presence of pivalic (trimethylacetic) anhydride under H2. Less hindered aliphatic and aromatic acids are reduced to aldehydes in high yields The method is also applicable to hydrogenation of dibasic carboxylic acids and carboxylic acids containing heterocyclic groups.

UR - http://www.scopus.com/inward/record.url?scp=0032273263&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032273263&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0032273263

SP - 1143

EP - 1144

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 11

ER -