Direct observation of the kinetic behavior of a charge-transfer reaction on the cation-scavenging reaction for cation radicals of N-vinylcarbazole and N-ethylcarbazole by using a pulse radiolysis technique

M. Washio, S. Tagawa, Y. Tabata

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The cation-scavenging reaction has been directly observed by using the pulse radiolysis method for cation radicals of both N-vinylcarbazole (VCZ+·; the initiating species of radiation-induced cationic polymerization of VCZ) and N-ethylcarbazole (EtCZ+·, nonpolymerizing model compound) in order to elucidate the role of inhibitors in radiation-induced cationic polymerization. The rate constants for the reactions of VCZ+· with triethylamine, diphenylamine, and dimethylaniline in nitrobenzene solution have been determined to be 1.3 × 109, 2.0 × 109, and 3.9 × 109 M-1 s-1, respectively, which are almost the same as those for EtCZ+· with these three scavengers.

Original languageEnglish
Pages (from-to)2876-2879
Number of pages4
JournalJournal of physical chemistry
Volume84
Issue number22
DOIs
Publication statusPublished - 1980 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

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