Direct proline-catalyzed asymmetric α-aminoxylation of ketones

Yujiro Hayashi; Junichiro Yamaguchi; Tatsunobu Sumiya; Mitsuru Shoji

doi:10.1002/anie.200353085

Direct proline-catalyzed asymmetric α-aminoxylation of ketones

Yujiro Hayashi^*, Junichiro Yamaguchi, Tatsunobu Sumiya, Mitsuru Shoji

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

273 Citations (Scopus)

Abstract

Nitrosobenzene is the oxygen source in the direct catalytic enantioselective α-aminoxylation of ketones catalyzed by L-proline [Eq. (1)]. Versatile α-aminoxylated ketones are obtained in high yield and with excellent enantioselectivities.

Original language	English
Pages (from-to)	1112-1115
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	9
DOIs	https://doi.org/10.1002/anie.200353085
Publication status	Published - 2004 Feb 20
Externally published	Yes

Keywords

Asymmetric catalysis
Ketones
Oxidation
Proline

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200353085

Cite this

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title = "Direct proline-catalyzed asymmetric α-aminoxylation of ketones",

abstract = "Nitrosobenzene is the oxygen source in the direct catalytic enantioselective α-aminoxylation of ketones catalyzed by L-proline [Eq. (1)]. Versatile α-aminoxylated ketones are obtained in high yield and with excellent enantioselectivities.",

keywords = "Asymmetric catalysis, Ketones, Oxidation, Proline",

author = "Yujiro Hayashi and Junichiro Yamaguchi and Tatsunobu Sumiya and Mitsuru Shoji",

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doi = "10.1002/anie.200353085",

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T1 - Direct proline-catalyzed asymmetric α-aminoxylation of ketones

AU - Hayashi, Yujiro

AU - Yamaguchi, Junichiro

AU - Sumiya, Tatsunobu

AU - Shoji, Mitsuru

PY - 2004/2/20

Y1 - 2004/2/20

N2 - Nitrosobenzene is the oxygen source in the direct catalytic enantioselective α-aminoxylation of ketones catalyzed by L-proline [Eq. (1)]. Versatile α-aminoxylated ketones are obtained in high yield and with excellent enantioselectivities.

AB - Nitrosobenzene is the oxygen source in the direct catalytic enantioselective α-aminoxylation of ketones catalyzed by L-proline [Eq. (1)]. Versatile α-aminoxylated ketones are obtained in high yield and with excellent enantioselectivities.

KW - Asymmetric catalysis

KW - Ketones

KW - Oxidation

KW - Proline

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U2 - 10.1002/anie.200353085

DO - 10.1002/anie.200353085

M3 - Article

C2 - 14983448

AN - SCOPUS:4243057730

SN - 1433-7851

VL - 43

SP - 1112

EP - 1115

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 9

ER -

Direct proline-catalyzed asymmetric α-aminoxylation of ketones

Abstract

Keywords

ASJC Scopus subject areas

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