Direct Synthesis of Highly Designable Hybrid Metal Hydroxide Nanosheets by Using Tripodal Ligands as One-Size-Fits-All Modifiers

Yoshiyuki Kuroda, Tatsuyuki Koichi, Keisuke Muramatsu, Kazuya Yamaguchi, Noritaka Mizuno, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda

    Research output: Contribution to journal › Article

    9 Citations (Scopus)

    Abstract

    Brucite-type layered metal hydroxides are prepared from diverse metallic elements and have outstanding functions; however, their poor intercalation ability significantly limits their chemical designability and the use of their potentially ultrahigh surface areas and unique properties as two-dimensional nanosheets. Here, we demonstrate that tripodal ligands (RC(CH2OH)3, R=NH2, CH2OH, or NHC2H4SO3H) are useful as "one-size-fits-all" modifiers for the direct synthesis of hybrid metal hydroxide nanosheets with various constituent metallic elements (M=Mg, Mn, Fe, Co, Ni, or Cu) and surface functional groups. The hybrid nanosheets are formed directly from solution phases, and they are stacked into a turbostratic layered structure. The ligands form tridentate Mg-O-C bonds with brucite layers. The hybrid brucite intercalates various molecules and is exfoliated into nanosheets at room temperature, although the non-modified material does not intercalate any molecules. Consequently, both the constituent metallic elements and surface functional groups are freely designed by the direct synthesis.

    Original languageEnglish
    JournalChemistry - A European Journal
    DOIs
    Publication statusAccepted/In press - 2017

    Fingerprint

    Magnesium Hydroxide
    Nanosheets
    Metals
    Ligands
    Chemical elements
    Functional groups
    Hydroxides
    Molecules
    Intercalation
    hydroxide ion
    Temperature

    Keywords

    • Brucite-type structures
    • Hybrid materials
    • Layered metal hydroxides
    • Nanostructures
    • Tripodal ligands

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Direct Synthesis of Highly Designable Hybrid Metal Hydroxide Nanosheets by Using Tripodal Ligands as One-Size-Fits-All Modifiers. / Kuroda, Yoshiyuki; Koichi, Tatsuyuki; Muramatsu, Keisuke; Yamaguchi, Kazuya; Mizuno, Noritaka; Shimojima, Atsushi; Wada, Hiroaki; Kuroda, Kazuyuki.

    In: Chemistry - A European Journal, 2017.

    Research output: Contribution to journal › Article

    Kuroda, Y, Koichi, T, Muramatsu, K, Yamaguchi, K, Mizuno, N, Shimojima, A, Wada, H & Kuroda, K 2017, 'Direct Synthesis of Highly Designable Hybrid Metal Hydroxide Nanosheets by Using Tripodal Ligands as One-Size-Fits-All Modifiers', Chemistry - A European Journal. https://doi.org/10.1002/chem.201605698
    Kuroda Y, Koichi T, Muramatsu K, Yamaguchi K, Mizuno N, Shimojima A et al. Direct Synthesis of Highly Designable Hybrid Metal Hydroxide Nanosheets by Using Tripodal Ligands as One-Size-Fits-All Modifiers. Chemistry - A European Journal. 2017. https://doi.org/10.1002/chem.201605698
    Kuroda, Yoshiyuki ; Koichi, Tatsuyuki ; Muramatsu, Keisuke ; Yamaguchi, Kazuya ; Mizuno, Noritaka ; Shimojima, Atsushi ; Wada, Hiroaki ; Kuroda, Kazuyuki. / Direct Synthesis of Highly Designable Hybrid Metal Hydroxide Nanosheets by Using Tripodal Ligands as One-Size-Fits-All Modifiers. In: Chemistry - A European Journal. 2017.
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