Direct synthesis of intercalation compounds between a layered double hydroxide and an anionic dye

In Yong Park; Kazuyuki Kuroda; Chuzo Kato

doi:10.1039/DT9900003071

Direct synthesis of intercalation compounds between a layered double hydroxide and an anionic dye

In Yong Park, Kazuyuki Kuroda, Chuzo Kato^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

Intercalation compounds between a layered double hydroxide and an anionic dye were directly synthesized by hydrolysis of mixed solutions of aluminium nitrate, magnesium nitrate, and the anionic dyes (indigo carmine or new coccine). The intercalated indigo carmine anions are possibly arranged with their molecular planes perpendicular to the hydroxide layers. The basal spacings of the new coccine intercalates suggested that the configuration of the new coccine anions in the interlayers changed upon washing. Intercalation of the dyes by anion exchange from layered double hydroxides with NO₃^- or Cl^- as the interlayer anions was also conducted for comparison.

Original language	English
Pages (from-to)	3071-3074
Number of pages	4
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	10
DOIs	https://doi.org/10.1039/DT9900003071
Publication status	Published - 1990 Dec 1

ASJC Scopus subject areas

Chemistry(all)

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10.1039/DT9900003071

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abstract = "Intercalation compounds between a layered double hydroxide and an anionic dye were directly synthesized by hydrolysis of mixed solutions of aluminium nitrate, magnesium nitrate, and the anionic dyes (indigo carmine or new coccine). The intercalated indigo carmine anions are possibly arranged with their molecular planes perpendicular to the hydroxide layers. The basal spacings of the new coccine intercalates suggested that the configuration of the new coccine anions in the interlayers changed upon washing. Intercalation of the dyes by anion exchange from layered double hydroxides with NO3- or Cl- as the interlayer anions was also conducted for comparison.",

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N2 - Intercalation compounds between a layered double hydroxide and an anionic dye were directly synthesized by hydrolysis of mixed solutions of aluminium nitrate, magnesium nitrate, and the anionic dyes (indigo carmine or new coccine). The intercalated indigo carmine anions are possibly arranged with their molecular planes perpendicular to the hydroxide layers. The basal spacings of the new coccine intercalates suggested that the configuration of the new coccine anions in the interlayers changed upon washing. Intercalation of the dyes by anion exchange from layered double hydroxides with NO3- or Cl- as the interlayer anions was also conducted for comparison.

AB - Intercalation compounds between a layered double hydroxide and an anionic dye were directly synthesized by hydrolysis of mixed solutions of aluminium nitrate, magnesium nitrate, and the anionic dyes (indigo carmine or new coccine). The intercalated indigo carmine anions are possibly arranged with their molecular planes perpendicular to the hydroxide layers. The basal spacings of the new coccine intercalates suggested that the configuration of the new coccine anions in the interlayers changed upon washing. Intercalation of the dyes by anion exchange from layered double hydroxides with NO3- or Cl- as the interlayer anions was also conducted for comparison.

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Direct synthesis of intercalation compounds between a layered double hydroxide and an anionic dye

Abstract

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