Disordered Jahn-Teller-polaron states in the simple perovskite manganite Ca1−xLaxMnO3 with 0.15 ≦ x ≦ 0.28

Tomoki Endo, Takamasa Goto, Yasuhide Inoue, Yasumasa Koyama

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Among orbital-ordered states in manganites with strongly correlated electronic systems, both the C-type orbital-ordered (Ctype-OO) state and the charge- and orbital-ordered (COO) state have been reported in the simple perovskite Ca1xLaxMnO3 (CLMO) with 0.15 ≦ x ≦ 0.28. To understand their formation from the disordered Pnma (DO) state with orthorhombic symmetry, the crystallographic features of prepared CLMO samples with 0.15 ≦ x ≦ 0.28 were examined mainly by transmission electron microscopy. When the temperature was lowered from the orthorhombic DO state for 0.15 ≦ x ≦ 0.23, referred to as Region I, the Ctype-OO state with monoclinic-P21=m symmetry appeared via a disordered Jahn-Teller polaron (DJTP) state, which exhibited characteristic diffuse scattering around each DO reflection in electron diffraction patterns. For 0.23 ≦ x ≦ 0.28 as Region II, cooling from the DO state resulted in the appearance of the COO state via a similar DJTP state. In patterns obtained from the COO state, satellite reflections characterizing the state were confirmed to be due to both transverse and longitudinal lattice modulations. It was also found that the DJTP states in Regions I and II were present in TN ≧ T ≧ TCtype-OO and T ≧ TCOO, respectively, and were identified as the precursor states, which appear prior to the formation of the Ctype-OO and COO states.

Original languageEnglish
Article number074708
Journaljournal of the physical society of japan
Volume88
Issue number7
DOIs
Publication statusPublished - 2019 Jan 1

Fingerprint

orbitals
symmetry
diffraction patterns
electron diffraction
cooling
modulation
transmission electron microscopy
scattering
electronics
temperature

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Disordered Jahn-Teller-polaron states in the simple perovskite manganite Ca1−xLaxMnO3 with 0.15 ≦ x ≦ 0.28. / Endo, Tomoki; Goto, Takamasa; Inoue, Yasuhide; Koyama, Yasumasa.

In: journal of the physical society of japan, Vol. 88, No. 7, 074708, 01.01.2019.

Research output: Contribution to journalArticle

@article{19c741ab3973405ea21b6d3cf62c7508,
title = "Disordered Jahn-Teller-polaron states in the simple perovskite manganite Ca1−xLaxMnO3 with 0.15 ≦ x ≦ 0.28",
abstract = "Among orbital-ordered states in manganites with strongly correlated electronic systems, both the C-type orbital-ordered (Ctype-OO) state and the charge- and orbital-ordered (COO) state have been reported in the simple perovskite Ca1−xLaxMnO3 (CLMO) with 0.15 ≦ x ≦ 0.28. To understand their formation from the disordered Pnma (DO) state with orthorhombic symmetry, the crystallographic features of prepared CLMO samples with 0.15 ≦ x ≦ 0.28 were examined mainly by transmission electron microscopy. When the temperature was lowered from the orthorhombic DO state for 0.15 ≦ x ≦ 0.23, referred to as Region I, the Ctype-OO state with monoclinic-P21=m symmetry appeared via a disordered Jahn-Teller polaron (DJTP) state, which exhibited characteristic diffuse scattering around each DO reflection in electron diffraction patterns. For 0.23 ≦ x ≦ 0.28 as Region II, cooling from the DO state resulted in the appearance of the COO state via a similar DJTP state. In patterns obtained from the COO state, satellite reflections characterizing the state were confirmed to be due to both transverse and longitudinal lattice modulations. It was also found that the DJTP states in Regions I and II were present in TN ≧ T ≧ TCtype-OO and T ≧ TCOO, respectively, and were identified as the precursor states, which appear prior to the formation of the Ctype-OO and COO states.",
author = "Tomoki Endo and Takamasa Goto and Yasuhide Inoue and Yasumasa Koyama",
year = "2019",
month = "1",
day = "1",
doi = "10.7566/JPSJ.88.074708",
language = "English",
volume = "88",
journal = "Journal of the Physical Society of Japan",
issn = "0031-9015",
publisher = "Physical Society of Japan",
number = "7",

}

TY - JOUR

T1 - Disordered Jahn-Teller-polaron states in the simple perovskite manganite Ca1−xLaxMnO3 with 0.15 ≦ x ≦ 0.28

AU - Endo, Tomoki

AU - Goto, Takamasa

AU - Inoue, Yasuhide

AU - Koyama, Yasumasa

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Among orbital-ordered states in manganites with strongly correlated electronic systems, both the C-type orbital-ordered (Ctype-OO) state and the charge- and orbital-ordered (COO) state have been reported in the simple perovskite Ca1−xLaxMnO3 (CLMO) with 0.15 ≦ x ≦ 0.28. To understand their formation from the disordered Pnma (DO) state with orthorhombic symmetry, the crystallographic features of prepared CLMO samples with 0.15 ≦ x ≦ 0.28 were examined mainly by transmission electron microscopy. When the temperature was lowered from the orthorhombic DO state for 0.15 ≦ x ≦ 0.23, referred to as Region I, the Ctype-OO state with monoclinic-P21=m symmetry appeared via a disordered Jahn-Teller polaron (DJTP) state, which exhibited characteristic diffuse scattering around each DO reflection in electron diffraction patterns. For 0.23 ≦ x ≦ 0.28 as Region II, cooling from the DO state resulted in the appearance of the COO state via a similar DJTP state. In patterns obtained from the COO state, satellite reflections characterizing the state were confirmed to be due to both transverse and longitudinal lattice modulations. It was also found that the DJTP states in Regions I and II were present in TN ≧ T ≧ TCtype-OO and T ≧ TCOO, respectively, and were identified as the precursor states, which appear prior to the formation of the Ctype-OO and COO states.

AB - Among orbital-ordered states in manganites with strongly correlated electronic systems, both the C-type orbital-ordered (Ctype-OO) state and the charge- and orbital-ordered (COO) state have been reported in the simple perovskite Ca1−xLaxMnO3 (CLMO) with 0.15 ≦ x ≦ 0.28. To understand their formation from the disordered Pnma (DO) state with orthorhombic symmetry, the crystallographic features of prepared CLMO samples with 0.15 ≦ x ≦ 0.28 were examined mainly by transmission electron microscopy. When the temperature was lowered from the orthorhombic DO state for 0.15 ≦ x ≦ 0.23, referred to as Region I, the Ctype-OO state with monoclinic-P21=m symmetry appeared via a disordered Jahn-Teller polaron (DJTP) state, which exhibited characteristic diffuse scattering around each DO reflection in electron diffraction patterns. For 0.23 ≦ x ≦ 0.28 as Region II, cooling from the DO state resulted in the appearance of the COO state via a similar DJTP state. In patterns obtained from the COO state, satellite reflections characterizing the state were confirmed to be due to both transverse and longitudinal lattice modulations. It was also found that the DJTP states in Regions I and II were present in TN ≧ T ≧ TCtype-OO and T ≧ TCOO, respectively, and were identified as the precursor states, which appear prior to the formation of the Ctype-OO and COO states.

UR - http://www.scopus.com/inward/record.url?scp=85068478325&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85068478325&partnerID=8YFLogxK

U2 - 10.7566/JPSJ.88.074708

DO - 10.7566/JPSJ.88.074708

M3 - Article

AN - SCOPUS:85068478325

VL - 88

JO - Journal of the Physical Society of Japan

JF - Journal of the Physical Society of Japan

SN - 0031-9015

IS - 7

M1 - 074708

ER -