TY - JOUR
T1 - Distribution of W and Mo in ordinary chondrites and implications for nebular and parent body thermal processes
AU - Kong, Ping
AU - Ebihara, Mitsuru
N1 - Funding Information:
We are indebtedto the ReactorC ommitteeo f the Universityo f Tokyo for the use of the facilities at the Institutef or Atomic Energy,R ikkyo University. Discussionw ith B. Fegley andt hec ommenbt y H.E. Newsoma ndK . Loddersw ash elpfuli n revisingt his paper.P . Kong is gratefult o the JSPS Fellowship. This work was partly supportedb y a Grant-in-Aid for ScientificR esearchfr om the Ministry of Education,S ciencea ndC ulture,J apan( 05453012to M.E.).
PY - 1996/1
Y1 - 1996/1
N2 - W and Mo abundances in the bulk metals of 10 H, 5 L and 6 LL chondrites were determined by instrumental neutron activation analysis (INAA). Partitioning of W and Mo between metal and non-metal phases was evaluated by comparing Ni-normalized W and Mo abundances in the metal phases with those in the bulk samples. It is observed that W distributions differ significantly between equilibrated ordinary chondrites (EOCs) and unequilibrated ordinary chondrites (UOCs). However, no correlation is confirmed between the W distribution and the petrographic type for EOCs. This implies that the W partitioning among mineral phases can provide a clue for estimating the metamorphic temperature intervening between EOCs and UOCs. The difference in W equilibrium temperatures was observed among H, L and LL chondrite groups and it may correspond to the difference in cooling rates and subsequently in sizes of the chondrite parent bodies; LL chondrites have the lowest equilibrium temperature and, hence, have the largest parent body, whereas H chondrites have the highest equilibrium temperature and the smallest parent body. Mo/W abundance ratios remain constant in EOC metals, but are variable in UOC metals, suggesting that the W solid equilibrium has not been achieved in UOCs. The W and Mo distributions in UOCs still preserve the characteristics of W and Mo in the nebula, which demonstrates that the chondritic metal was formed by melting highly oxidized precursors before or during the accretion of chondrite parent bodies.
AB - W and Mo abundances in the bulk metals of 10 H, 5 L and 6 LL chondrites were determined by instrumental neutron activation analysis (INAA). Partitioning of W and Mo between metal and non-metal phases was evaluated by comparing Ni-normalized W and Mo abundances in the metal phases with those in the bulk samples. It is observed that W distributions differ significantly between equilibrated ordinary chondrites (EOCs) and unequilibrated ordinary chondrites (UOCs). However, no correlation is confirmed between the W distribution and the petrographic type for EOCs. This implies that the W partitioning among mineral phases can provide a clue for estimating the metamorphic temperature intervening between EOCs and UOCs. The difference in W equilibrium temperatures was observed among H, L and LL chondrite groups and it may correspond to the difference in cooling rates and subsequently in sizes of the chondrite parent bodies; LL chondrites have the lowest equilibrium temperature and, hence, have the largest parent body, whereas H chondrites have the highest equilibrium temperature and the smallest parent body. Mo/W abundance ratios remain constant in EOC metals, but are variable in UOC metals, suggesting that the W solid equilibrium has not been achieved in UOCs. The W and Mo distributions in UOCs still preserve the characteristics of W and Mo in the nebula, which demonstrates that the chondritic metal was formed by melting highly oxidized precursors before or during the accretion of chondrite parent bodies.
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U2 - 10.1016/0012-821x(95)00208-t
DO - 10.1016/0012-821x(95)00208-t
M3 - Article
AN - SCOPUS:0029750429
SN - 0012-821X
VL - 137
SP - 83
EP - 93
JO - Earth and Planetary Sciences Letters
JF - Earth and Planetary Sciences Letters
IS - 1-4
ER -