DMAP-accelerated rhodium(I) chloride catalyzed hydroboration of vinylarenes

Kohei Endo, Munenao Hirokami, Kazunari Takeuchi, Takanori Shibata

    Research output: Contribution to journalArticle

    12 Citations (Scopus)

    Abstract

    Regioselective hydroboration of vinylarenes catalyzed by a Rh(I)-DPPB complex proceeded rapidly when DMAP was used as an additive. The catalyst loading could be reduced to 0.4 mol% Rh(I) to furnish the desired products in good to excellent yield with high regioselectivity.

    Original languageEnglish
    Pages (from-to)3231-3233
    Number of pages3
    JournalSynlett
    Issue number20
    DOIs
    Publication statusPublished - 2008 Dec 16

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    Keywords

    • Alkenes
    • Boron
    • Hydroborations
    • Regioselectivity
    • Rhodium

    ASJC Scopus subject areas

    • Organic Chemistry

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