DMAP-accelerated rhodium(I) chloride catalyzed hydroboration of vinylarenes

Kohei Endo, Munenao Hirokami, Kazunari Takeuchi, Takanori Shibata

    Research output: Contribution to journalArticle

    12 Citations (Scopus)

    Abstract

    Regioselective hydroboration of vinylarenes catalyzed by a Rh(I)-DPPB complex proceeded rapidly when DMAP was used as an additive. The catalyst loading could be reduced to 0.4 mol% Rh(I) to furnish the desired products in good to excellent yield with high regioselectivity.

    Original languageEnglish
    Pages (from-to)3231-3233
    Number of pages3
    JournalSynlett
    Issue number20
    DOIs
    Publication statusPublished - 2008 Dec 16

    Fingerprint

    Regioselectivity
    Rhodium
    Chlorides
    Catalysts

    Keywords

    • Alkenes
    • Boron
    • Hydroborations
    • Regioselectivity
    • Rhodium

    ASJC Scopus subject areas

    • Organic Chemistry

    Cite this

    DMAP-accelerated rhodium(I) chloride catalyzed hydroboration of vinylarenes. / Endo, Kohei; Hirokami, Munenao; Takeuchi, Kazunari; Shibata, Takanori.

    In: Synlett, No. 20, 16.12.2008, p. 3231-3233.

    Research output: Contribution to journalArticle

    Endo, Kohei ; Hirokami, Munenao ; Takeuchi, Kazunari ; Shibata, Takanori. / DMAP-accelerated rhodium(I) chloride catalyzed hydroboration of vinylarenes. In: Synlett. 2008 ; No. 20. pp. 3231-3233.
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